Transition-metal-catalyzed C-Ge coupling reactions

被引:4
作者
Ke, Jie [2 ,3 ]
Du Chen, Cadmus [2 ,3 ]
Ren, Li-Qing [2 ,3 ]
Zu, Bing [2 ,3 ]
Li, Bin [1 ]
He, Chuan [2 ,3 ]
机构
[1] Wuyi Univ, Sch Environm & Chem Engn, Jiangmen 529020, Guangdong, Peoples R China
[2] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China
[3] Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
X-H X; DEHYDROGENATIVE GERMYLATION; ORGANIC HALIDES; SILYLATION; INSERTION; SI; GERMANYLATION; SILICON; HYDROGERMYLATION; HYDROGEN;
D O I
10.1039/d4qo01637h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Given the significance of organogermanium compounds in materials science, medicinal chemistry, and synthetic chemistry, transition-metal-catalyzed C-Ge coupling reactions have become a focal point in organic synthesis, driving innovation in organogermane chemistry. This review examines the development and recent advancements in transition-metal-catalyzed C-Ge coupling reactions, aiming to provide new insights and inspire further research and applications in this rapidly evolving field. This review covers the development and recent progress in transition-metal-catalyzed C-Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.
引用
收藏
页码:6558 / 6572
页数:15
相关论文
共 70 条
[1]   Triply Selective & Sequential Diversification at Csp3: Expansion of Alkyl Germane Reactivity for C-C & C-Heteroatom Bond Formation [J].
Ahrweiler, Eric ;
Schoetz, Markus D. ;
Singh, Gurdeep ;
Bindschaedler, Quentin P. ;
Sorroche, Alba ;
Schoenebeck, Franziska .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (16)
[2]   Synthesis and Photodynamics of Tetragermatetrathia[8]circulene [J].
Akahori, Shuhei ;
Sakai, Hayato ;
Hasobe, Taku ;
Shinokubo, Hiroshi ;
Miyake, Yoshihiro .
ORGANIC LETTERS, 2018, 20 (01) :304-307
[3]   REACTIONS OF ORGANIC HALIDES WITH R3MMR3 COMPOUNDS (M=SI,GE,SN) IN PRESENCE OF TETRAKIS(TRIARYLPHOSPHINE) PALLADIUM [J].
AZARIAN, D ;
DUA, SS ;
EABORN, C ;
WALTON, DRM .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 117 (03) :C55-C57
[4]   Organometallic chemistry on silicon and germanium surfaces [J].
Buriak, JM .
CHEMICAL REVIEWS, 2002, 102 (05) :1271-1308
[5]   Palladium-Catalyzed Oxalyl Amide Directed Silylation and Germanylation of Amine Derivatives [J].
Chen, Changpeng ;
Guan, Mingyu ;
Zhang, Jingyu ;
Wen, Zhenkang ;
Zhao, Yingsheng .
ORGANIC LETTERS, 2015, 17 (15) :3646-3649
[6]   Carbon-Germanium Bond Formation via Low-Valent Cobalt- Catalyzed Cross-Electrophile Coupling [J].
Chen, Haifeng ;
Zhu, Chen ;
Yue, Huifeng ;
Rueping, Magnus .
ACS CATALYSIS, 2023, 13 (10) :6773-6780
[7]   From Quaternary Carbon to Tertiary C(sp3)-Si and C(sp3)-Ge Bonds: Decyanative Coupling of Malononitriles with Chlorosilanes and Chlorogermanes Enabled by Ni/Ti Dual Catalysis [J].
Chen, Zi-Hao ;
Zheng, Yu-Qing ;
Huang, Hong-Gui ;
Wang, Ke-Hao ;
Gong, Jun-Lin ;
Liu, Wen-Bo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (21) :14445-14452
[8]   Experimental and Computational Studies on Remote γ-C(sp3)-H Silylation and Germanylation of Aliphatic Carboxamides [J].
Deb, Arghya ;
Singh, Sukriti ;
Seth, Kapileswar ;
Pimparkar, Sandeep ;
Bhaskararao, Bangaru ;
Guin, Srimanta ;
Sunoj, Raghavan B. ;
Maiti, Debabrata .
ACS CATALYSIS, 2017, 7 (12) :8171-8175
[9]   Ligand-Controlled Regiodivergent Palladium-Catalyzed Hydrogermylation of Ynamides [J].
Debrauwer, Vincent ;
Turlik, Aneta ;
Rummler, Lenaic ;
Prescimone, Alessandro ;
Blanchard, Nicolas ;
Houk, K. N. ;
Bizet, Vincent .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (25) :11153-11164
[10]   THE ADDITION REACTION BETWEEN TRICHLOROGERMANE AND AN OLEFIN [J].
FISCHER, AK ;
WEST, RC ;
ROCHOW, EG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (22) :5878-5878