Boosting CO2 hydrogenation to light olefins with low CO selectivity through promoting HCOO* intermediates on Fe-ZnGa2O4/SAPO-34

被引：2
|
作者：
Sun, Zheyi [1 ]
Gao, Zihao [1 ]
Ma, Rongting [1 ]
Xu, Qingling [1 ]
Shao, Bin [1 ,2 ]
Liu, Honglai [1 ,3 ]
Hu, Jun [1 ]
机构：
[1] East China Univ Sci & Technol, Sch Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
[2] East China Univ Sci & Technol, Key Lab Smart Mfg Energy Chem Proc, Minist Educ, Sch Informat Sci & Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
[3] East China Univ Sci & Technol, State Key Lab Chem Engn, Sch Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
来源：
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY | 2024年 / 358卷
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Carbon dioxide hydrogenation; Light olefins; Bifunctional catalyst; Fe doping; ZnGa2O4; spinel; CARBON-DIOXIDE; CONVERSION; SYNGAS; PROPENE;
D O I：
10.1016/j.apcatb.2024.124358
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
CO2 hydrogenation to light olefins over oxide-zeolite (OX-ZEO) bifunctional catalysts has been considered as a promising solution towards Carbon Recycling, but still exists bottleneck problems in terms of low CO2 conversion efficiency and olefin yield. Facing to the challenges, we propose a strategy by stabilizing HCOO* intermediates and therefore inhibiting the COOH* pathway for the formation of CO byproducts through atomically doping Fe in ZnGa2O4 spinel. Various in situ characterizations and the dynamic analysis reveal quantitively that the highly dispersed Fe can facilitate the H* to attack the exposed C in adsorbed CO2* to enhance the CH3O* formation, promoting the consecutive olefin production. Coupling with SAPO-34, the optimized Fe-ZnGa2O4-2.5/SAPO-34 exhibits a high CO2 conversion efficiency of 26.6 % and C-2-C-4(=) yield of 12.5 % with an excellent stability for 200 h, providing a promising strategy for CO2 hydrogenation to light olefins.
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页数：9
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