Boosting CO2 hydrogenation to light olefins with low CO selectivity through promoting HCOO* intermediates on Fe-ZnGa2O4/SAPO-34

被引：2
|
作者：
Sun, Zheyi [1 ]
Gao, Zihao [1 ]
Ma, Rongting [1 ]
Xu, Qingling [1 ]
Shao, Bin [1 ,2 ]
Liu, Honglai [1 ,3 ]
Hu, Jun [1 ]
机构：
[1] East China Univ Sci & Technol, Sch Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
[2] East China Univ Sci & Technol, Key Lab Smart Mfg Energy Chem Proc, Minist Educ, Sch Informat Sci & Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
[3] East China Univ Sci & Technol, State Key Lab Chem Engn, Sch Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
来源：
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY | 2024年 / 358卷
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Carbon dioxide hydrogenation; Light olefins; Bifunctional catalyst; Fe doping; ZnGa2O4; spinel; CARBON-DIOXIDE; CONVERSION; SYNGAS; PROPENE;
D O I：
10.1016/j.apcatb.2024.124358
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
CO2 hydrogenation to light olefins over oxide-zeolite (OX-ZEO) bifunctional catalysts has been considered as a promising solution towards Carbon Recycling, but still exists bottleneck problems in terms of low CO2 conversion efficiency and olefin yield. Facing to the challenges, we propose a strategy by stabilizing HCOO* intermediates and therefore inhibiting the COOH* pathway for the formation of CO byproducts through atomically doping Fe in ZnGa2O4 spinel. Various in situ characterizations and the dynamic analysis reveal quantitively that the highly dispersed Fe can facilitate the H* to attack the exposed C in adsorbed CO2* to enhance the CH3O* formation, promoting the consecutive olefin production. Coupling with SAPO-34, the optimized Fe-ZnGa2O4-2.5/SAPO-34 exhibits a high CO2 conversion efficiency of 26.6 % and C-2-C-4(=) yield of 12.5 % with an excellent stability for 200 h, providing a promising strategy for CO2 hydrogenation to light olefins.
引用
收藏
页数：9
相关论文
共 50 条
  • [1] Electronic interaction promoting CO2 hydrogenation to light olefins over ZnZrOx/SAPO-34 catalyst
    Zhao, Yongjie
    Shi, Peixiang
    Wang, Xiaoyue
    Guo, Xiaohong
    Yao, Ruwei
    Li, Yanchun
    Jia, Qian
    Ban, Hongyan
    Li, Lei
    Li, Congming
    CHEMICAL ENGINEERING JOURNAL, 2025, 503
  • [2] Optimization of synthesis condition for CO2 hydrogenation to light olefins over In2O3 admixed with SAPO-34
    Numpilai, Thanapa
    Wattanakit, Chularat
    Chareonpanich, Metta
    Limtrakul, Jumras
    Witoon, Thongthai
    ENERGY CONVERSION AND MANAGEMENT, 2019, 180 : 511 - 523
  • [3] Production of light olefins by catalytic hydrogenation of CO2 over Y2O3/Fe-Co modified with SAPO-34
    Oni, Babalola Aisosa
    Sanni, Samuel Eshorame
    Ibegbu, Anayo Jerome
    APPLIED CATALYSIS A-GENERAL, 2022, 643
  • [4] Zn promoted GaZrOx Ternary Solid Solution Oxide Combined with SAPO-34 Effectively Converts CO2 to Light Olefins with Low CO Selectivity
    Liu, Shike
    Yang, Kun
    Ren, Qixia
    Liu, Fei
    Yao, Mengqin
    Ma, Jun
    Geng, Shuo
    Cao, Jianxin
    CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (39)
  • [5] Modulating the electronic interaction of ZnFemCrOx/SAPO-34 to boost CO2 hydrogenation to light olefins
    Cao, Zhifan
    Guo, Xiaohong
    Wang, Xiaoyue
    Shi, Peixiang
    Yan, Zhiqiang
    Ban, Hongyan
    Yao, Ruwei
    Li, Yanchun
    Li, Congming
    MOLECULAR CATALYSIS, 2024, 569
  • [6] Tandem Catalysis for Hydrogenation of CO and CO2 to Lower Olefins with Bifunctional Catalysts Composed of Spinel Oxide and SAPO-34
    Liu, Xiaoliang
    Wang, Mengheng
    Yin, Haoren
    Hu, Jingting
    Cheng, Kang
    Kang, Jincan
    Zhang, Qinghong
    Wang, Ye
    ACS CATALYSIS, 2020, 10 (15) : 8303 - 8314
  • [7] Tuning CO2 Hydrogenation to Light Olefin Selectivity via Cu/Zn/Zr Supported on Modified SAPO-34
    Lu, Peng
    Ali, Kime Mala
    Lin, Yitong
    Hu, Qianwen
    Yu, Wenjia
    Xing, Chuang
    Wang, Yanhong
    Wei, Qinhong
    CHEMISTRYSELECT, 2024, 9 (41):
  • [8] CO2 Hydrogenation to Light Olefins Over In2O3/SAPO-34 and Fe-Co/K-Al2O3 Composite Catalyst
    Numpilai, Thanapha
    Kahadit, Supitchaya
    Witoon, Thongthai
    Ayodele, Bamidele Victor
    Cheng, Chin Kui
    Siri-Nguan, Nuchanart
    Sornchamni, Thana
    Wattanakit, Chularat
    Chareonpanich, Metta
    Limtrakul, Jumras
    TOPICS IN CATALYSIS, 2021, 64 (5-6) : 316 - 327
  • [9] Synthesis of light olefins from CO2 hydrogenation over (CuO-ZnO)-kaolin/SAPO-34 molecular sieves
    Wang, Pengfei
    Zha, Fei
    Yao, Lu
    Chang, Yue
    APPLIED CLAY SCIENCE, 2018, 163 : 249 - 256
  • [10] Boosting CO2 hydrogenation performance for light olefin synthesis over GaZrOx combined with SAPO-34
    Zhang, Peng
    Ma, Lixuan
    Meng, Fanhui
    Wang, Lina
    Zhang, Riguang
    Yang, Guinan
    Li, Zhong
    APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2022, 305
12345