The pressure response of crystalline trans-cinnamic acid is studied by means of Raman spectroscopy up to 6 GPa. Pressure application causes the reversible shift of all the observed Raman peaks to higher frequencies and changes in their relative intensities, with the intermolecular vibrational modes being by far more sensitive to pressurization compared to the intramolecular ones. The present high-pressure Raman data indicate the structural stability of the trans-cinnamic acid crystal and molecular conformation up to the highest pressure attained in the experiments, the importance of the hydrogen bonding, as well as the considerable strengthening of the intermolecular interactions at elevated pressures.
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Colorado State Univ, Cell & Mol Biol Program, Ft Collins, CO USAColorado State Univ, Cell & Mol Biol Program, Ft Collins, CO USA
Hunstiger, Darcy
Ma, Hayley
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Colorado State Univ, Dept Chem & Biol Engn, 1370 Campus Delivery, Ft Collins, CO 80523 USA
Entegris Inc, Round Rock, TX USAColorado State Univ, Cell & Mol Biol Program, Ft Collins, CO USA
Ma, Hayley
Paton, Andrew J.
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Colorado State Univ, Dept Biol, Ft Collins, CO USAColorado State Univ, Cell & Mol Biol Program, Ft Collins, CO USA
Paton, Andrew J.
Peebles, Christie A. M.
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Colorado State Univ, Cell & Mol Biol Program, Ft Collins, CO USA
Colorado State Univ, Dept Chem & Biol Engn, 1370 Campus Delivery, Ft Collins, CO 80523 USAColorado State Univ, Cell & Mol Biol Program, Ft Collins, CO USA
机构:
Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R ChinaSichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
Jiang, Xiaodong
Lei, Li
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Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
Sichuan Univ, Key Lab High Energy Dens Phys & Technol, Minist Educ, Chengdu 610065, Peoples R ChinaSichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
Lei, Li
Hu, Qiwei
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Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R ChinaSichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
Hu, Qiwei
Feng, Zhe Chuan
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Natl Taiwan Univ, Inst Photon & Optoelect, Dept Elect Engn, Taipei 10617, TaiwanSichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
Feng, Zhe Chuan
He, Duanwei
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Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
Sichuan Univ, Key Lab High Energy Dens Phys & Technol, Minist Educ, Chengdu 610065, Peoples R ChinaSichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China