Carbonaceous adsorbents in wastewater treatment: From mechanism to emerging application

Adsorption is of great significance in the water pollution control. Carbonaceous adsorbents, such as carbon quantum dots, carbon nanotubes, graphene, and activated carbons, have long been deployed in sustainable wastewater treatment due to their excellent physical structure and strong interaction with various pollutants; these features allow them to spark greater interest in environmental remediation. Although numerous eye-catch researches on carbon materials in wastewater treatment, there is a lack of comprehensive comparison and summary of the vivid structure-activity-application relationships of different types of carbonaceous adsorbents at the molecular and atomic level. Herein, this review aims to scrutinize and contrast the adsorption mechanisms of carbonaceous adsorbents with different dimensions, analyzing the qualitative differences in adsorption capacity from microscopic perspectives, structural diversity caused by preparation methods, and environmental external factors affecting adsorption occurrence. Then, a quantitatively in-depth critical appraisal of traditional and emerging contaminants in wastewater treatment using carbonaceous adsorbents, and innovative strategies for enhancing their adsorption capacity are discussed. Finally, in the context of growing imposed circularity and zero waste wishes, this review offers some promising insights for carbonaceous adsorbents in achieving sustainable wastewater treatment. © 2024 Elsevier B.V.