Room temperature gas sensors for NH3 detection based on the heterojunction of 2D Ti3C2Tx MXenes and Bi2S3

被引:2
作者
Zhao, Zhihua [1 ]
Su, Zijie [1 ]
Lv, Zhenli [1 ]
Shi, Pu [1 ]
Jin, Guixin [2 ]
Wu, Lan [1 ]
机构
[1] Henan Univ Technol, Coll Mech & Elect Engn, Zhengzhou 450052, Peoples R China
[2] Hanwei Elect Grp Corp, Zhengzhou 450052, Peoples R China
基金
中国国家自然科学基金;
关键词
NH3; Ti3C2Tx MXene; Bi2S3; Gas sensor; Moisture resistance; AMMONIA GAS; SENSITIVITY;
D O I
10.1007/s00604-024-06750-1
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Bi2S3/Ti3C2Tx nanomaterials were successfully prepared through a simple hydrothermal method. Various methods were used for their characterization, including XRD, XPS, SEM, EDS, and BET, along with testing their gas-sensing properties. The results showed that the response value to 100 ppm ammonia at room temperature reached 107%, which was 14.1 times higher than that of pure few-layer MXene. After undergoing anti-humidity interference testing, we observed that Bi2S3/Ti3C2Tx exhibited a higher response value in real-time monitoring of ammonia as humidity increased. Specifically, under 90% humidity conditions, its response value reached 1.32 times that of normal humidity conditions. This exceptional moisture resistance ensures that the sensor can maintain stability, and even exhibit superior performance, in harsh environments. Therefore, it possesses excellent selectivity, high-moisture-resistance, and long-term stability, making it significant in the field of medical and health monitoring.
引用
收藏
页数:13
相关论文
共 52 条
[1]   Flexible NH3 3 gas sensors based on ZnO nanostructures deposited on kevlar substrates via hydrothermal method [J].
Aydas, Bahadir ;
Atilgan, Abdullah ;
Ajjaq, Ahmad ;
Acar, Selim ;
Oktem, Mehmet Fatih ;
Yildiz, Abdullah .
CERAMICS INTERNATIONAL, 2024, 50 (18) :32477-32489
[2]   MXene-based gas sensors [J].
Bhardwaj, Radha ;
Hazra, Arnab .
JOURNAL OF MATERIALS CHEMISTRY C, 2021, 9 (44) :15735-15754
[3]   Enhanced ammonia sensing performance based on MXene-Ti3C2Tx multilayer nanoflakes functionalized by tungsten trioxide nanoparticles [J].
Guo, Xuezheng ;
Ding, Yanqiao ;
Kuang, Delin ;
Wu, Zhilin ;
Sun, Xia ;
Du, Bingsheng ;
Liang, Chengyao ;
Wu, Yingjie ;
Qu, Weijie ;
Xiong, Lian ;
He, Yong .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 595 :6-14
[4]   MXene/SnS2 Heterojunction for Detecting Sub-ppm NH3 at Room Temperature [J].
He, Tingting ;
Sun, Shupeng ;
Huang, Baoyu ;
Li, Xiaogan .
ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (03) :4194-4207
[5]   MXene/SnO2 heterojunction based chemical gas sensors [J].
He, Tingting ;
Liu, Wei ;
Lv, Tan ;
Ma, Mingsheng ;
Liu, Zhifu ;
Vasiliev, Alexey ;
Li, Xiaogan .
SENSORS AND ACTUATORS B-CHEMICAL, 2021, 329
[6]   Solid Lubrication Performance of Few- and Multilayer Ti3C2Tx Coatings [J].
Hurtado, Jose Y. Aguilar ;
Gruetzmacher, Philipp G. ;
Henriquez, Javier Marques ;
Zambrano, Dario ;
Wang, Bo ;
Rosenkranz, Andreas .
ADVANCED ENGINEERING MATERIALS, 2022, 24 (10)
[7]   Metallic Ti3C2TX MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio [J].
Kim, Seon Joon ;
Koh, Hyeong-Jun ;
Ren, Chang E. ;
Kwon, Ohmin ;
Maleski, Kathleen ;
Cho, Soo-Yeon ;
Anasori, Babak ;
Kim, Choong-Ki ;
Choi, Yang-Kyu ;
Kim, Jihan ;
Gogotsi, Yury ;
Jung, Hee-Tae .
ACS NANO, 2018, 12 (02) :986-993
[8]   Enhanced room temperature ammonia response of 2D-Ti3C2Tx MXene decorated with Ni(OH)2 nanoparticles [J].
Kuang, Delin ;
Guo, Xuezheng ;
Zhu, ZeTao ;
Ding, Yanqiao ;
Sun, Xia ;
Wu, Zhilin ;
Zhang, Luwen ;
Zhou, Yangyang ;
He, Yong .
CERAMICS INTERNATIONAL, 2021, 47 (14) :19471-19480
[9]   Deposition of Bi2S3 thin films from heterocyclic bismuth(III) dithiocarbamato complexes [J].
Kun, Walter N. ;
Mlowe, Sixberth ;
Nyamen, Linda D. ;
Akerman, Matthew P. ;
O'Brien, Paul ;
Ndifon, Peter T. ;
Revaprasadu, Neerish .
POLYHEDRON, 2018, 154 :173-181
[10]  
Lee B., 2021, Membr J, V31, DOI [10.14579/membrane_journal.2021.31.5.304, DOI 10.14579/MEMBRANEJOURNAL.2021.31.5.304]