In situ construction of W-doped Co-P electrocatalyst by electrodeposition for boosting alkaline water/seawater hydrogen evolution reaction

The development of an efficient yet cost-effective non-precious electrocatalyst for the hydrogen evolution reaction (HER) in alkaline water and seawater systems remains a formidable obstacle to the large-scale production of hydrogen energy, stemming from the sluggish kinetics of electron transfer reactions during the HER process. In this article, an amorphous Co-P-W electrocatalyst on nickel foam is prepared using a brief cyclic voltammetry (CV) electrodeposition method. The optimized Co-P-W electrocatalyst exhibits excellent electrocatalytic performance for HER, which only requires overpotentials of 59 and 143 mV to achieve a current density of 10 mA cm(-2) in alkaline water (1.0 M KOH) and alkaline seawater (1.0 M KOH + natural seawater), respectively, and remarkable stability and durability. The improved HER performance of the Co-P-W electrocatalyst is attributed to the introduction of W, which modulates the electronic structure of Co and P, optimizes the adsorption/dissociation of H2O, and reduces the charge transfer resistance of the Co-P electrocatalyst, thus improving the kinetics of the HER. Furthermore, the W-doping significantly enhances the hydrophilicity of the Co-P electrocatalyst, which favors rapid and thorough penetration of electrolytes into the electrocatalyst, facilitating the formation of a highly accessible reaction interface, ultimately resulting in excellent HER activity. Our findings demonstrate the feasibility of designing an efficient, durable, and scalable electrocatalyst to significantly boost HER efficiency for practical water electrolysis.