Liquid Viscosity and Surface Tension of Cyclohexane Between 280 and 473 K by Surface Light Scattering

被引：0
作者：
Damp, Paul [1 ,2 ]
Sun, Yongzhen [1 ,2 ]
Schulz, Peter S. [3 ]
Koller, Thomas M. [1 ,2 ]
Froeba, Andreas P. [1 ,2 ]
机构：
[1] Friedrich Alexander Univ Erlangen Nurnberg FAU, Dept Chem & Biol Engn CBI, Paul Gordan Str 8, D-91052 Erlangen, Germany
[2] Friedrich Alexander Univ Erlangen Nurnberg FAU, Inst Adv Opt Technol Thermophys Properties AOT TP, Erlangen Grad Sch Adv Opt Technol SAOT, Paul Gordan Str 8, D-91052 Erlangen, Germany
[3] Friedrich Alexander Univ Erlangen Nurnberg FAU, Inst Chem React Engn CRT, Dept Chem & Biol Engn CBI, Egerlandstr 3, D-91058 Erlangen, Germany
来源：
INTERNATIONAL JOURNAL OF THERMOPHYSICS | 2024年 / 45卷 / 11期
关键词：
Cyclohexane; Surface light scattering; Surface tension; Vapor-liquid equilibrium; Viscosity; THERMOPHYSICAL PROPERTIES; DILUTE-SOLUTIONS; BINARY-MIXTURES; IONIC LIQUIDS; N-HEXADECANE; ALKANES; DODECANE; DENSITY; OCTANE;
D O I：
10.1007/s10765-024-03453-w
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The present study provides experimental data for the liquid viscosity and surface tension of cyclohexane at or close to saturation conditions by surface light scattering between (280 and 473) K. By applying the hydrodynamic theory for surface fluctuations at the vapor-liquid phase boundary, which could be verified experimentally, the liquid viscosity and surface tension were determined simultaneously at macroscopic thermodynamic equilibrium with average relative expanded (k = 2) uncertainties of Ur(eta ') = 0.020 and Ur(sigma) = 0.012. For both properties, the present measurement results agree well with reference values in the literature which are restricted to a maximum temperature of 393 K for viscosity and 337 K for surface tension. The experimental results from this work contribute to an improved database for the viscosity and surface tension of cyclohexane over a wide temperature range from a temperature close to the melting point up to 473 K.
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页数：15
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