Synthesis and Properties of 1-Hydroxy-N-(1H-1,2,4-triazol-3-yl)-1H-tetrazole-5-carboxamide

被引：0
作者：
Liu J. [1 ]
Dong Y.-Q. [1 ]
Li M. [1 ]
Liu Y.-J. [1 ]
Huang W. [1 ]
Tang Y.-X. [1 ]
机构：
[1] School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing
来源：
Hanneng Cailiao/Chinese Journal of Energetic Materials | 2023年 / 31卷 / 12期
基金：
中国国家自然科学基金;
关键词：
1‐hydroxy‐N‐（1H‐12,4‐triazol‐3‐yl）‐1H‐tetrazole‐5‐carboxamide; amide bond; nitrogen-rich heterocyclic energetic compounds; tetrazole; triazole;
D O I：
10.11943/CJEM2023141
中图分类号：
学科分类号：
摘要：
In order to explore novel nitrogen-rich heterocyclic energetic compounds,an amide bridged energetic compound 1-hydroxy-N(- 1H-1,2,4-triazol-3-yl)-1H-tetrazole-5-carboxamide was synthesized from 5-cyano-1- (1H-1,2,4-triazol-5-yl)-1H-tetrazole through several steps involving amidoximation,diazotization,substitution and electrophilic addition. Its structure was fully characterized by nuclear magnetic resonance(NMR),Fourier transform infrared spectroscopy(FT-IR)and elemental analysis(EA). X-ray diffraction analysis(SC-XRD)was adopted to further confirm its structure;its thermal decomposition process was studied by differential scanning calorimetry(DSC)and thermogravimetry(TG). The compound has a high onset decomposition temperature of 265 ℃ and shows good properties with detonation velocity of 8017 m·s-1,and detonation pressure of 23.1 GPa,impact sensitivity of 20 J,and friction sensitivity of 288 N. © 2023 Institute of Chemical Materials, China Academy of Engineering Physics. All rights reserved.
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页码：1198 / 1205
页数：7
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