Redox-mediated photocatalysis towards separate hydrogen production and sulfide oxidation

被引：0

作者：

Li, Rui ^{[1
]}

Lv, Fei ^{[1
]}

Jin, Xiaodan ^{[1
]}

Wang, Pengfei ^{[1
]}

Chen, Yubin ^{[1
]}

机构：

[1] Xi An Jiao Tong Univ, Int Res Ctr Renewable Energy, State Key Lab Multiphase Flow Power Engn, Xian, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 86期

基金：

中国国家自然科学基金;

关键词：

Z-SCHEME; WATER; H2S;

D O I：

10.1039/d4cc03492a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present a redox-mediated photocatalysis for separate hydrogen production and sulfide oxidation. The process involves photocatalytic hydrogen production and Fe(CN)64- oxidation, followed by spontaneous Fe(CN)63- reduction and sulfide oxidation to valued sulfur. In this approach, Fe(CN)64-/3- redox mediators were recycled, and the produced sulfur wouldn't interfere with the photocatalytic performance. A redox-mediated approach involving photocatalytic and galvanic cells was proposed to achieve spatially separated hydrogen production and sulfide oxidation.

引用

页码：12565 / 12568

页数：4

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