Roles of carbon dioxide in the conversion of biomass or waste plastics

Under the current trend of pursuing sustainable development and environmental protection, the important application of carbon dioxide (CO2) in the conversion process of biomass or waste plastics has become a research direction of concern. The goal of this conversion process is to achieve the efficient use of carbon dioxide, providing a process for the efficient use of biomass, and solving the environmental problems caused by plastics. Remarkable progress has been made in the study of the reaction of CO2 with other substances to produce methane, low-carbon hydrocarbons, methanol, formic acid, and its derivatives, as well as ethers, aldehydes, gasoline, low-carbon alcohols, and other chemicals. In this paper, the important role of CO2 in the conversion of alcohol, sugar, cellulose, and waste plastics was reviewed, with emphasis on the important applications of CO2 as a carbon source, reactant, reaction medium, enhancing agent, solvent, and carrier gas in the conversion of biomass or waste plastics and the basic insights of the reaction mechanism. The emerging CO2 new roles not only put forward the green application of CO2 but also have guiding significance for the utilization of biomass resources and the treatment of waste plastics. © 2024 Elsevier B.V.