Reducing corrosion and hydrogen gas release inside an alkaline zinc-air battery by employing ionic liquid

被引:1
|
作者
Deyab, M. A. [1 ]
Mohsen, Q. [2 ]
机构
[1] Egyptian Petr Res Inst EPRI, Nasr City, Cairo, Egypt
[2] Taif Univ, Coll Sci, Dept Chem, Taif, Saudi Arabia
关键词
Zinc-air battery; Corrosion; Hydrogen gas; Ionic liquid; Discharge capacity; Capacity retention; ELECTROCHEMICAL ENERGY-STORAGE; SULFURIC-ACID; CARBON-STEEL; MILD-STEEL; INHIBITION; PASSIVATION; SURFACTANT; BEHAVIOR; PERFORMANCE; OPERATION;
D O I
10.1016/j.electacta.2024.145207
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Zn-air batteries are a promising route that might be used in a range of energy sectors. Significant disadvantages, such as passive film and hydrogen gas evolution (HGE) in alkaline corrosive medium; restrict the possible usage of Zn-air batteries. To address these problems and increase the performance of zinc-air batteries, an ionic liquid (tris(2hydroxyethyl) hydroxymethylammonium methyl sulfate [IL]+[MS]-) has been used in this study. The usage of [IL]+[MS]- in 7.0 M KOH solution has a considerable effect on suppressing hydrogen gas creation, with an effectiveness of 86.2 %. Increasing the depth of the Bode-phase angle and the charge transfer resistance by adding [IL]+[MS]- also indicates a slower hydrogen gas production rate. The application of the [IL]+[MS]- additive improves the zinc-air battery's specific discharge capacity and capacity retention. To support these findings, SEM/EDX has been used to analyze the morphological features of Zn anodes in various electrolytes.
引用
收藏
页数:8
相关论文
共 27 条
  • [1] The Influence of Dimethyl Sulfoxide as Electrolyte Additive on Anodic Dissolution of Alkaline Zinc-Air Flow Battery
    Hosseini, Soraya
    Abbasi, Ali
    Uginet, Luc-Olivier
    Haustraete, Nicolas
    Praserthdam, Supareak
    Yonezawa, Tetsu
    Kheawhom, Soorathep
    SCIENTIFIC REPORTS, 2019, 9 (1)
  • [2] Suppression of zinc anode corrosion for printed flexible zinc-air battery
    Wongrujipairoj, Krittaporn
    Poolnapol, Laksanaporn
    Arpornwichanop, Amornchai
    Suren, Sira
    Kheawhom, Soorathep
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2017, 254 (02):
  • [3] Electronic and Ionic Conductivities Enhancement of Zinc Anode for Flexible Printed Zinc-Air Battery
    Chotipanich, Jutamart
    Arpornwichanop, Amornchai
    Yonezawa, Tetsu
    Kheawhom, Soorathep
    ENGINEERING JOURNAL-THAILAND, 2018, 22 (02): : 47 - 57
  • [4] Systematic cycle life assessment of a secondary zinc-air battery as a function of the alkaline electrolyte composition
    Mainar, Aroa R.
    Iruin, Elena
    Colmenares, Luis C.
    Blazquez, J. Alberto
    Grande, Hans-Jurgen
    ENERGY SCIENCE & ENGINEERING, 2018, 6 (03): : 174 - 186
  • [5] Li/air Flow Battery Employing Ionic Liquid Electrolytes
    Grande, Lorenzo
    Ochel, Anders
    Monaco, Simone
    Mastragostino, Marina
    Tonti, Dino
    Palomino, Pablo
    Paillard, Elie
    Passerini, Stefano
    ENERGY TECHNOLOGY, 2016, 4 (01) : 85 - 89
  • [6] Selective Ion Transporting Polymerized Ionic Liquid Membrane Separator for Enhancing Cycle Stability and Durability in Secondary Zinc-Air Battery Systems
    Hwang, Ho Jung
    Chi, Won Seok
    Kwon, Ohchan
    Lee, Jin Goo
    Kim, Jong Hak
    Shul, Yong-Gun
    ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (39) : 26298 - 26308
  • [7] Ag/C nanoparticles as an cathode catalyst for a zinc-air battery with a flowing alkaline electrolyte
    Han, Jia-Jun
    Li, Ning
    Zhang, Tian-Yun
    JOURNAL OF POWER SOURCES, 2009, 193 (02) : 885 - 889
  • [8] Mitigating hydrogen evolution reaction and corrosion of zinc in electrically rechargeable zinc-air batteries using nanofluid electrolytes
    Subramaniam, Thiruvenkatam
    Idris, Mustapha Balarabe
    Suganthi, K. S.
    Rajan, K. S.
    Devaraj, S.
    JOURNAL OF ENERGY STORAGE, 2024, 81
  • [9] Water-suspended graphene as electrolyte additive in zinc-air alkaline battery system
    K. Kishore Kumar
    R. Brindha
    M. Nandhini
    M. Selvam
    K. Saminathan
    K. Sakthipandi
    Ionics, 2019, 25 : 1699 - 1706
  • [10] Water-suspended graphene as electrolyte additive in zinc-air alkaline battery system
    Kumar, K. Kishore
    Brindha, R.
    Nandhini, M.
    Selvam, M.
    Saminathan, K.
    Sakthipandi, K.
    IONICS, 2019, 25 (04) : 1699 - 1706