Preparation and lithium storage performance of rice-like core-shell FeS2/C nanoparticles

被引:0
|
作者
Xia Q. [1 ,2 ,3 ]
Xu Y. [1 ,2 ]
Zhou Y. [1 ]
Ji X. [1 ]
Feng H. [1 ,2 ]
Wang P. [1 ,2 ]
Tan Q. [1 ,2 ,4 ]
机构
[1] State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing
[2] Zhongke Langfang Institute of Process Engineering, Langfang Economic & Technical Development Zone, Langfang
[3] Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing
[4] Hebei Technology Innovation Center of Advanced Energy Materials, Langfang
来源
Huagong Xuebao/CIESC Journal | 2021年 / 72卷 / 05期
关键词
Composites; Core-shell structure; Electrochemistry; Iron disulfide; Lithium ion batteries; Nanomaterials;
D O I
10.11949/0438-1157.20201507
中图分类号
学科分类号
摘要
The rice grain-like FeS2/C nanomaterial with core-shell structure was prepared by anion displacement reaction. The prepared composite shows enhanced inoic and electronic conductivity, excellent electrolyte infiltration characteristics, and capability of buffering the volume change. When evaluated as anode of lithium ion batteries, the FeS2/C electrodes exhibit high reversible capacity of 1100 mA•h•g-1 at 100 mA•g-1 and outstanding rate capability. Even at high current density of 2 A•g-1, a reversible capacity of 866 mA•h•g-1 can be achieved. The results in this paper provide new ideas and methods for the preparation of other core-shell materials. © 2021, Editorial Board of CIESC Journal. All right reserved.
引用
收藏
页码:2849 / 2856
页数:7
相关论文
共 34 条
  • [1] Tarascon J M, Armand M., Issues and challenges facing rechargeable lithium batteries, Nature, 414, 6861, pp. 359-367, (2001)
  • [2] Goodenough J B, Kim Y., Challenges for rechargeable batteries, Chem. Mater, 22, 3, pp. 587-603, (2010)
  • [3] Zhang W J., A review of the electrochemical performance of alloy anodes for lithium-ion batteries, Journal of Power Sources, 196, 1, pp. 13-24, (2011)
  • [4] Cheng X B, Zhang R, Zhao C Z, Et al., Toward safe lithium metal anode in rechargeable batteries: a review, Chemical Reviews, 117, 15, pp. 10403-10473, (2017)
  • [5] Wang D K, Zhou C L, Cao B, Et al., One-step synthesis of spherical Si/C composites with onion-like buffer structure as high-performance anodes for lithium-ion batteries, Energy Storage Materials, 24, pp. 312-318, (2020)
  • [6] Liu Z H, Yu Q, Zhao Y L, Et al., Silicon oxides: a promising family of anode materials for lithium-ion batteries, Chemical Society Reviews, 48, 1, pp. 285-309, (2019)
  • [7] Song J H, Xiao D D, Jia H P, Et al., A comparative study of pomegranate Sb@C yolk-shell microspheres as Li and Na-ion battery anodes, Nanoscale, 11, 1, pp. 348-355, (2018)
  • [8] Wang H, Wu X, Qi X J, Et al., Sb nanoparticles encapsulated in 3D porous carbon as anode material for lithium-ion and potassium-ion batteries, Materials Research Bulletin, 103, pp. 32-37, (2018)
  • [9] Xia Q, Zhao H L, Du Z H, Et al., Facile synthesis of MoO<sub>3</sub>/carbon nanobelts as high-performance anode material for lithium ion batteries, Electrochimica Acta, 180, pp. 947-956, (2015)
  • [10] Li R, Xiao W, Miao C, Et al., Sphere-like SnO<sub>2</sub>/TiO<sub>2</sub> composites as high-performance anodes for lithium ion batteries, Ceramics International, 45, 10, pp. 13530-13535, (2019)