Carbene-Catalyzed [3+3] Annulation of Enals and Vinyl Sulfoxonium Ylides

被引：0

作者：

Feng, Siru ^{[1
]}

Zhang, Hailong ^{[1
]}

Liu, Jinhua ^{[1
]}

Shi, Dongping ^{[1
]}

Yang, Weiqi ^{[1
]}

Zhu, Haibin ^{[1
]}

Zhang, Xiaoxiang ^{[2
]}

Fu, Zhenqian ^{[1
]}

机构：

[1] Nanjing Tech Univ, Inst Adv Mat, Nanjing 211816, Peoples R China

[2] Nanjing Forestry Univ, Coll Chem Engn, Coinnovat Ctr Efficient Proc & Utilizat Forest Res, Nanjing 210037, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 19期

基金：

中国国家自然科学基金;

关键词：

ENANTIOSELECTIVE SYNTHESIS;

D O I：

10.1021/acs.joc.4c01587

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbene-catalyzed [3 + 3] annulation of enals and vinyl sulfoxonium ylides has been demonstrated. This method efficiently synthesizes a range of 2-sulfenylidene-3-cyclohexen-1-ones with high atom economy. Notably, the presence of the sulfoxonium ylide moiety in the obtained products significantly enhances their potential for further synthetic transformations.

引用

页码：14537 / 14542

页数：6

共 59 条

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