Research Progress and Applications of Energetic Coordination Compounds

被引：0
|
作者：
Qi X. [1 ]
Han X. [1 ]
Wan Z. [1 ]
Zhang L. [1 ]
Yi Z. [1 ]
Zhu S. [1 ]
机构：
[1] School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing
来源：
Hanneng Cailiao/Chinese Journal of Energetic Materials | 2022年 / 30卷 / 03期
关键词：
Energetic coordination compounds; Energetic coordination polymers; Energetic metal‑organic framework; Nitrogen‑rich ligands;
D O I：
10.11943/CJEM2021118
中图分类号：
学科分类号：
摘要：
Energy Coordination Compound (ECC) has become one of the research hotspots in recent years because of its diverse Coordination modes between different metal elements and ligands, and it is expected to obtain energetic materials with highly adjustable properties. In this paper, the ways and types of assembling ECC with different ligands are reviewed, and the applications of ECC and its functional materials as initiators, propellant catalysts, flammable agents and oxidants of thermite, pyrotechnics colorants are reviewed. Studies have shown that the energetic complexes formed after the coordination of different metal ions and nitrogen‑rich ligands show great potential in the field of new energetic materials, and can meet the requirements of energy, sensitivity and other properties through the change of the type and number of ligands. The law of ECC synthesis is summarized and how to improve the energy characteristics and expand the application in the future is prospected. © 2022, Editorial Board of Chinese Journal of Energetic Materials. All right reserved.
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页码：276 / 288
页数：12
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  • [41] Liu X Y, Yang Q., Et al., 3D high‑energy‑density and low sensitivity materials: Synthesis, structure and physicochemical properties of an azide‑Cu(II) complex with 3, 5‑dinitrobenzoic acid, RSC Advvances, 4, pp. 16087-1609, (2014)
  • [42] Gu H, Huang S L, Ma Q, Et al., Gem‑dinitromethyl‑substituted energetic metal‑organic framework based on 1, 2, 3‑triazole from in situ controllable synthesis, Chemistry‑An Asian Journal, 13, pp. 2786-2790, (2018)
  • [43] Fischer D, Klapctke T M, Stierstorfer J., Dikalium‑1, 1'‑dinitramino‑5, 5'‑bistetrazolat‑ein Primärsprengstoff mit schneller Detonation und hoher Initiierungsleistung, Angewandte Chemie International Edition, 126, pp. 8311-8314, (2014)
  • [44] Kunz S C, Salas F J., Diode laser ignition of high explosives and pyrotechnics, Proceedings of the 13th International Pyrotechnics Seminar, pp. 505-523, (1988)
  • [45] Merson J A., Salas F J, Harlan J G., The development of laser ignited deflagration‑to‑detonation transition (DDT) detonators and pyrotechnic actuators, Proceedings of the 19th International Pyrotechnics Seminar, pp. 191-206, (1994)
  • [46] Myers T W, Bjorgaard J A, Brown K E, Et al., Energetic chromophores: Low‑energy laser initiation in explosive Fe(II) tetrazine complexes, Journal of the American Chemical Society, 138, pp. 4685-4692, (2016)
  • [47] Wang T W, Zhang Q, Deng H, Et al., Evolution of oxidizing inorganic metal salts: Ultrafast laser initiation materials based on energetic cationic coordination polymers, ACS Applied Materials & Interfaces, 11, 44, pp. 41523-41530, (2019)
  • [48] Wurzenberger M H H, Klapoetke T M, Lommel M, Et al., Comparison of 1‑propyl‑5H‑tetrazole and 1‑azidopropyl‑5H‑tetrazole as ligands for laser ignitable energetic materials, ACS Applied Energy Materials, 3, pp. 3798-3806, (2020)
  • [49] Stierstorfer J, Szimhardt N, Wurzenberger M H H, Et al., Maximization of the energy capability level in transition metal complexes through application of 1‑amino‑ and 2‑amino‑5H‑tetrazole ligands, Journal of Materials Chemistry A, 6, pp. 16257-16272, (2018)
  • [50] Zeisel L, Szimhardt N, Wurzenberger M H H, Et al., 2‑Methyl‑substituted monotetrazoles in copper(II) perchlorate complexes: Manipulating coordination chemistry and derived energetic properties, New Journal of Chemistry, 43, pp. 609-616, (2019)
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