Unveiling the role of oxygen vacancy of manganese oxide coating on Ni foam to magnetocaloric catalytic oxidation of toluene

Using a pulsed-voltage technique, the manganese oxide (MnOx) coating on Ni foam (NF) was regulated to encourage magnetocaloric oxidation, which lowers volatile organic compounds (VOCs). The MnOx/NF was obtained by electrodeposition of MnOx onto NF. Subsequently, MnOx/NF-PV was obtained by pulsed-voltage modification. According to the structural characterization, the pulsed-voltage modification changed the interaction between the coating and the support, resulting in increased toluene adsorption capacity, oxygen desorption capability, oxygen vacancy (OV) quantity of MnOx/NF-PV. The MnOx/NF-PV exhibits excellent catalytic performance, with a 90 % conversion of toluene at 170 degrees C, where OV play an important role as electronic intermediates in magnetocaloric oxidation reactions. Furthermore, compared to traditional thermal catalysis, electromagnetic induction heating (EMIH) can promote the reactivity of OV in magnetocaloric catalysts by increasing the activation and dissociation of oxygen species and thus catalytic activity, which was demonstrated in the 18 O isotope exchange experiment.