The formation process and influencing factors of electric field-induced oxygen vacancy in Y2O3 transparent ceramic

被引:2
|
作者
Zhang, Keying [1 ,2 ]
Li, Tianyu [1 ,2 ]
Liu, Xuejian [1 ]
Huang, Zhengren [1 ]
Liu, Yan [1 ,2 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine M, Shanghai 200050, Peoples R China
[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
关键词
Electric field-induced oxygen vacancy; Transparent ceramic; Influencing factors; EPR; X-ray photoelectron spectroscopy; FLASH; TEMPERATURE; ZIRCONIA;
D O I
10.1016/j.ceramint.2024.07.456
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Oxygen vacancy is the key contributing to the rapid bonding in flash joining. Prior to this study, the specific formation process of oxygen vacancy and its influencing factors have not been systematically investigated. In this work, the based materials yttrium oxide and Ti are phased observed during the incubation stage and the flash stage of flash joining. Three periods are summarized to reveal the whole process and variation in oxygen vacancy generation, electron binding, and metal filling. Following the stable stage, the factors impacting the oxygen vacancy are systematically studied and characterized to quantify their contribution. These factors include bonding temperature, current density, joining time, furnace atmosphere, and electric field direction. These findings have significant implications for precisely controlling the strength of the transparent/metal flash joint, meanwhile, may have reference value for universal flash joining.
引用
收藏
页码:41417 / 41425
页数:9
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