Enhancing β-phase and dielectric properties of BCZT lead-free reinforced in PVDF-HFP composite thick films for eco-friendly energy harvesting

Barium titanate doped with calcium and zirconium (BCZT) relaxor ferroelectric ceramics enhance energy storage capabilities due to their excellent ferroelectric and dielectric properties. In this investigation, BCZT particles (Ps) were incorporated into poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) using the solvent casting method to prepare biocompatible composite films with varying BCZT Ps contents. The uniform dispersion and distribution of BCZT Ps throughout the polymer matrix results in robust interfacial interactions, promoting improved nucleation of the beta-phase in PVDF-HFP and increased thermal stability with higher BCZT Ps loading. The Young's modulus and tensile strength of the composites experienced respective increases of 78.2 % and 41.8 % with the addition of 20 wt% BCZT Ps. While the dielectric constant was improved from 12 to 31. This research contributes to the development of flexible composite films with different BCZT Ps contents, to promote an innovative and environmentally friendly energy harvesting technology. This innovation captures environmental vibrations and converts them into electrical energy to supply a variety of sensors.