INVESTIGATION OF REPAIRING PEROVSKITE SOLAR CELLS VIA FORWARD BIAS VOLTAGE

被引：0
作者：
Zheng Z. [1 ,2 ]
Wang R. [1 ,2 ]
Huang S. [1 ,2 ]
Hang C. [1 ,2 ]
Wu J. [1 ,2 ]
Cheng S. [1 ,2 ,3 ]
机构：
[1] College of Physics and Information Engineering, Fuzhou University, Fuzhou
[2] Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou
[3] Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou
来源：
Taiyangneng Xuebao/Acta Energiae Solaris Sinica | 2024年 / 45卷 / 04期
关键词：
bias voltage; ion migration; perovskite solar cells; repair;
D O I：
10.19912/j.0254-0096.tynxb.2023-1293
中图分类号：
学科分类号：
摘要：
Forward bias voltage is utilized to regulate ion migration in perovskite solar cells（PSCs），thereby preventing the accumulation of perovskite ions at the interface，passivating defects，and restoring the performance of aged PSCs. The power conversion efficiency（PCE）of the aged PSCs is restored from 17.8% to 21.5% by implementing the forward bias voltage repair method. Introducing the bias voltage repair method in the maximum power point tracking for 100 hours yielded a total energy gain of 3.1%. An independently constructed integrated characterization environment was used to measure the real- time changes in the electrical and optical characteristics of PSCs before and after the repair process using bias voltage. Furthermore，a physical model was developed to investigate the mechanism behind the repair process，specifically focusing on the regulation of perovskite ion migration by bias voltage. The results demonstrate that the repairing strategy can control ion migration，passivate defects，optimize carrier extraction and transport，and ultimately repair the PSCs. © 2024 Science Press. All rights reserved.
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页码：59 / 64
页数：5
相关论文
共 16 条
  • [11] LI X Y, DONG H Y, XIA T, Et al., Investigation of post-treatment via tri-iodine ions for perovskite solar cells［J］, Acta energiae solaris sinica, 44, 3, pp. 409-414, (2023)
  • [12] LI D M，, Et al., Interfaces in perovskite solar cells［J］, Small, 11, 21, pp. 2472-2486, (2015)
  • [13] HEGEDUS S S, SHAFARMAN W N., Thin- film solar cells： device measurements and analysis［J］, Progress in photovoltaics：research and applications, 12, 2/3, pp. 155-176, (2004)
  • [14] YIN W J, YAN Y F., Unusual defect physics in CH3NH3PbI3 perovskite solar cell absorber［J］, Applied physics letters, 104, 6, (2014)
  • [15] TRESS W，, MARINOVA N，, MOEHL T，, Et al., Understanding the rate- dependent J- V hysteresis，slow time component， and aging in CH3NH3PbI3 perovskite solar cells：the role of a compensated electric field［J］, Energy & environmental science, 8, 3, pp. 995-1004, (2015)
  • [16] JIANG Y T，, CHEN D，, SUN Z H, Et al., Effect of Cu/Ag in ITO/Metal/ITO laminated electrode on performance of perovskite solar cells［J］, Acta energiae solaris sinica, 43, 9, pp. 83-87, (2022)
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