Facile synthesis, characterization and optical properties of Ag2WO4 incorporated g-C3N4 hybrid composites for H2 production

被引:0
作者
Kavitha, T. [1 ]
Renukadevi, S. [1 ]
Veerasamy, R. [2 ,3 ]
机构
[1] KSR Coll Engn, Dept Phys, Tiruchengode 637215, Tamilnadu, India
[2] Karpagam Acad Higher Educ, Dept Chem, Coimbatore 641064, Tamilnadu, India
[3] KSR Coll Engn, Dept Chem, Tiruchengode 637215, Tamilnadu, India
关键词
GRAPHITIC CARBON NITRIDE; VISIBLE-LIGHT; PHOTOCATALYTIC ACTIVITY; NANOSHEETS; HETEROJUNCTION; NANOPARTICLES; NANOCOMPOSITE; DISINFECTION; PERFORMANCE; REMOVAL;
D O I
10.1007/s10854-024-13569-2
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The hydrothermal approach was used to synthesise a composite photocatalyst of Ag2WO4/g-C3N4. This photocatalyst proved effective in preventing Escherichia coli (E. coli) when exposed to visible light. Imaging microscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), N-2 adsorption-desorption analysis, UV-Vis diffuse reflectance spectra (DRS), and photoluminescence (PL) were among the many methods used to comprehensively characterize the photocatalysts' physicochemical characteristics. In comparison to pure g-C3N4 and Ag2WO4 under visible light, the produced photocatalysts demonstrated significantly improved photocatalytic cleaning efficiency. In addition, under visible light irradiation for 60 min, a mixture of 5 percent Ag2WO4 and 100 milligrammes of g-C3N4 was able to entirely kill many live bacteria. The ideal mass ratio for this combination was 5 weight percent. By working in tandem, g-C3N4 and Ag2WO4 increase the separation rate of photogenerated electron-hole pairs and ensure that Ag2WO4 particles are evenly distributed over the g-C3N4 surface, leading to a high disinfection efficiency. These hybrids outperform pure g-C3N4 in the visible range when it comes to the efficiency of hydrogen evolution (3761.1 mu mol h(-1) g(-1)). A higher degree of photocatalytic activity may be achieved in the composite Ag2WO4/g-C3N4 photocatalyst through boosting the spacing of charge carriers produced by photons in the two photocatalysts.
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页数:14
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