Effects of BN surface modification on thermal conductivity of BN/epoxy composites

被引:0
|
作者
Wang W. [1 ]
Cao W. [2 ]
Chen T. [2 ]
机构
[1] College of Materials and Textile Engineering, Jiaxing University, Jiaxing
[2] Zhejiang Rongtai Technical Industry Co. Ltd., Jiaxing
关键词
BN; Composites; Epoxy resin; Surface modification; Thermal conductivity;
D O I
10.13801/j.cnki.fhclxb.20170509.002
中图分类号
学科分类号
摘要
Octadecyltrimethyl ammonium bromide (OTAB) was used as a cationic surfactant to modify micron BN platelets with an organic surface. The effects of BN surface modification on the thermal conductivity of BN/epoxy composites were studied. The adsorption of OTAB on BN surface is close to saturation at OTAB concentration of 0.6 g·L-1. BN surface modification improves the wettability of epoxy resin on BN surface and decreases the thermal conductivity of BN. SEM and viscosity characterization show that the interfacial and compatible properties of BN/epoxy composites are improved by the surface modification of BN. Due to the decrease in interfacial thermal resistance, the thermal conductivity of the modified BN/epoxy composites is higher than original BN/epoxy composites. When the filler loading is 30% (mass ratio of filler to matrix resin), the thermal conductivity of the modified BN/epoxy composite is 1.03 W(m·K)-1, 2.15 times of the thermal conductivity (0.48 W(m·K)-1) of original BN/epoxy composites. © 2018, Editorial Office of Acta Materiae Compositae Sinica. All right reserved.
引用
收藏
页码:275 / 281
页数:6
相关论文
共 22 条
  • [1] Li Q., Chen L., Gadinski M.R., Et al., Flexible high-temperature dielectric materials from polymer nanocomposites, Nature, 523, 7562, pp. 576-579, (2015)
  • [2] Chen J., Wang C., Wang Y., Et al., Effects of nano Al<sub>2</sub>O<sub>3</sub> distribution on thermal conductivity and mechanical property of Al<sub>2</sub>O<sub>3</sub>/PE-EVA composites, Acta Materiae Compositae Sinica, 32, 5, pp. 1286-1293, (2015)
  • [3] Zhou W., Ding X., Thermal Conductive Polymer Materials, pp. 28-34, (2014)
  • [4] Chen J., Huang X.Y., Zhu Y.K., Et al., Cellulose nano-fiber supported 3D interconnected BN nanosheets for epoxy composites with ultrahigh thermal management capability, Advanced Functional Materials, 27, 5, (2016)
  • [5] Qiao L., Zhao H., Zheng J., Et al., Effects of alumina platelets on thermal conductivity of Al<sub>2</sub>O<sub>3</sub>/FEP composites, Acta Materiae Compositae Sinica, 26, 6, pp. 37-41, (2009)
  • [6] Wang W., Xia Y., Research on heat conductive insulating material and its application, Insulating Materials, 45, 1, pp. 19-24, (2012)
  • [7] Jiang Q., Li H., Chen H., Technology and Application of Insulating Resin Material, pp. 11-15, (2013)
  • [8] Song S.S., Katagi H., Takezawa Y., Study on high thermal conductivity of mesogenic epoxy resin with spherulite structure, Polymer, 53, 20, pp. 4489-4492, (2012)
  • [9] Zhang X., Liu C., Li J., Et al., Research and application progress of filled-type resin-based thermal conductive insulating composites, Insulating Materials, 48, 3, pp. 8-11, (2015)
  • [10] Li H., Zhong Y., Wu W., Et al., Progress in filled epoxy resin-based thermal conductive composites, Adhesion, 36, 4, pp. 83-86, (2015)