Degradation of tetracycline hydrochloride using dielectric barrier discharge plasma reactor

被引:0
作者
Wang B. [1 ]
Wang C. [1 ]
Xu Y. [1 ]
Peng Y. [1 ]
Yao S. [1 ]
机构
[1] Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin
来源
Huagong Xuebao/CIESC Journal | 2018年 / 69卷 / 04期
关键词
Degradation; Dielectric barrier discharge; Mechanism; Oxidation; Tetracycline hydrochloride; Wastewater;
D O I
10.11949/j.issn.0438-1157.20170878
中图分类号
学科分类号
摘要
A dielectric barrier discharge plasma reactor was applied to the degradation of tetracycline hydrochloride in the aqueous solution. A series of parameters including input power, air-gap distance, initial concentration and air flow rate were investigated for their effects on the degradation efficiency. The results showed that the degradation efficiency was as high as 92% at the optimum degradation parameters: input power 1.3 W, air-gap distance 2.5 mm, air flow rate 150 ml•min-1, tetracycline hydrochloride initial concentration 100 mg•L-1 and treatment time 30 min. The kinetic studies indicated that the degradation of tetracycline hydrochloride followed the pseudo-second-order kinetics. Based on the intermediate products identified by LC-MS, a possible degradation pathway of tetracycline hydrochloride was proposed. © All Right Reserved.
引用
收藏
页码:1687 / 1694
页数:7
相关论文
共 31 条
[1]  
Magureanu M., Mandache N.B., Parvulescu V.I., Plasma treatment, Water Research, 81, pp. 124-136, (2015)
[2]  
Marti E., Huerta B., Rodriguez-Mozaz S., Et al., Characterization of ciprofloxacin-resistant isolates from a wastewater treatment plant and its receiving river, Water Research, 61, pp. 67-76, (2014)
[3]  
Magureanu M., Piroi D., Mandache N.B., Et al., Degradation of pharmaceutical compound pentoxifylline in water by non-thermal plasma treatment, Water Research, 44, 11, pp. 3445-3453, (2010)
[4]  
Stratton G.R., Bellona C.L., Dai F., Et al., Plasma-based water treatment: conception and application of a new general principle for reactor design, Chemical Engineering Journal, 273, pp. 543-550, (2015)
[5]  
Qu G.Z., Li J., Liang D.L., Et al., Research progress in organic wastewater treatment by low-temperature plasma discharge technology, Chemical Industry and Engineering Progress, 3, pp. 662-670, (2012)
[6]  
Jiang B., Zheng J., Liu Q., Et al., Degradation of azo dye using non-thermal plasma advanced oxidation process in a circulatory airtight reactor system, Chemical Engineering Journal, 204-206, pp. 32-39, (2012)
[7]  
Feng J., Zheng Z., Sun Y., Et al., Degradation of diuron in aqueous solution by dielectric barrier discharge, Journal of Hazardous Materials, 154, 1-3, pp. 1081-1089, (2008)
[8]  
Vanraes P., Willems G., Nikiforov A., Et al., Removal of atrazine in water by combination of activated carbon and dielectric barrier discharge, Journal of Hazardous Materials, 299, pp. 647-655, (2015)
[9]  
Kim K., Kam S.K., Mok Y.S., Elucidation of the degradation pathways of sulfonamide antibiotics in a dielectric barrier discharge plasma system, Chemical Engineering Journal, 271, pp. 31-42, (2015)
[10]  
Hijosa-Valsero M., Molina R., Schikora H., Et al., Removal of cyanide from water by means of plasma discharge technology, Water Research, 47, 4, pp. 1701-1707, (2013)