A novel energetic material hydrazinium 3, 5-dinitroamino-1, 2, 4-triazole: synthesis and properties

被引：0
作者：
Zhou, Cheng [1 ]
Wang, Bo-Zhou [1 ]
Huo, Huan [1 ]
Zhou, Qun [1 ]
Yang, Wei [1 ]
Ye, Zhi-Hu [1 ]
机构：
[1] Xi'an Modern Chemistry Research Institute, Xi'an
来源：
Hanneng Cailiao/Chinese Journal of Energetic Materials | 2014年 / 22卷 / 04期
关键词：
Hydrazonium of 3; 5-dinitroamine-1; 2; 4-triazole; (HDNAT); Organic chemistry; Property; Synthesis;
D O I：
10.3969/j.issn.1006-9941.2014.04.027
中图分类号：
学科分类号：
摘要：
A novel energetic material, hydrazinium 3, 5-dinitroamino-1, 2, 4-triazole (HDNAT) was designed and synthesized for the first time via condensation, nitrification and hydrazinolysis reaction with a total yield of 63.69%. It's structure was characterized by 1H NMR, 13C NMR, FT-IR and elemental analysis. In addition, some main properties of physico-chemistry and detonation for HDNAT were obtained by test or calculation. Results show that its density is 1.89 g·cm-3, melting point 194-196℃, friction sensitivity 92%, impact sensitivity 100%, H50 26.8 cm, detonation velocity 9000 m·s-1 (ρ=1.80 g·cm-3) and detonation pressure 36.0 GPa calculated with VLM method.
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页码：576 / 578
页数：2
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共 17 条
  • [1] Li G.-Q., Li Y.-C., Ma Q.-L., Et al., Research progress in synthesis of nitrogen-rich zole-ring compounds by cycloaddition reaction, Chinese Journal of Organic Chemistry, 30, 10, pp. 1431-1440, (2010)
  • [2] Liu X.-J., Zhang H.-J., Lin Q.-H., Et al., Progress of study on the synthesis of azole energetic ionic compounds, Chinese Journal of Explosives & Propellant, 33, 1, pp. 6-10, (2010)
  • [3] Lee K., Storm C., Hiskey M., Et al., An improved synthesis of 5-amino-3-nitro-1H-1, 2, 4-triazole (ANTA), a useful intermediate for the preparation of insensitive high explosives, Journal of Energetic Materials, 9, 5, pp. 415-428, (1991)
  • [4] Wang X.-J., Jia S.-Y., Wang B.-Z., Et al., Synthesis improvement of 5-amino-3-nitro-1, 2, 4-triazole (ANTA), Chinese Journal of Energetic Materials (Hanneng Cailiao), 14, 6, pp. 439-440, (2006)
  • [5] Zhu Z.-Y., Cao Y.-L., Sun Z.-X., Et al., Investigation on synthesis and properties of 5, 5'-dinitro-3, 3'-azo-1-hydro-1, 2, 4-triazole (DNAT), Journal of Solid Rocket Technology, 31, 5, pp. 501-503, (2008)
  • [6] Xia Y.-X., Wang P., Sun J., Et al., Synthesis and properties of 4-amino-1, 2, 4-triazole picrate, Fine Chemicals, 25, 5, pp. 445-448, (2008)
  • [7] Zhang H.-H., Jia S.-Y., Wang B.-Z., Et al., Synthesis and characterization of 3-amino (nitro)-5-nitro-1, 2, 4-triazole derivatives, Chinese Journal of Energetic Materials (Hanneng Cailiao), 18, 1, pp. 29-33, (2010)
  • [8] He Y., Fan G.-J., Zhang G.-Q., Et al., Review on synthesis and reactivity of 5-amino-3- nitro-1, 2, 4-trizole, Chinese Journal of Energetic Materials (Hanneng Cailiao), 20, 6, pp. 715-720, (2012)
  • [9] Zhou Q., Wang B.-Z., Jia S.-Y., New synthetic of 1-methyl-3-amino-5-nitro- 1, 2, 4-triazole, Chinese Journal of Energetic Materials (Hanneng Cailiao), 20, 1, pp. 26-29, (2012)
  • [10] Li L., Chi Y., Zhang Y., Et al., Synthesis, characterization and crystal structure of 4, 4'-bis-1, 2, 4-trizole, Chinese Journal of Energetic Materials (Hanneng Cailiao), 21, 4, pp. 429-433, (2013)
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