Luminescence properties and energy transferfrom Pr3+ to Yb3+ in GdBO3:Pr3+, Yb3+

被引:0
作者
Zhu, Fan [1 ]
You, Fang-Tian [1 ]
Shi, Qiu-Feng [1 ]
Peng, Hong-Shang [1 ]
Huang, Shi-Hua [1 ]
机构
[1] Key Laboratory of Luminescence and Optical Information, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing
来源
Faguang Xuebao/Chinese Journal of Luminescence | 2015年 / 36卷 / 07期
关键词
Energy transfer; GdBO[!sub]3[!/sub; Near infrared; Rare earth ions;
D O I
10.3788/fgxb20153607.0751
中图分类号
学科分类号
摘要
GdBO3:Pr3+ and GdBO3:Pr3+, Yb3+ samples were prepared by solid state reaction at high temperature. XRD patterns, excitation spectra and emission spectra in the Vis-NIR range of the obtained samples were studied in detail at room temperature. The emission of 2F5/2→2F7/2 (980 nm) of Yb3+ was observed under 446 nm excitation, indicating the occurrence of the energy transfer from Pr3+ to Yb3+. The fluorescence intensities varied with different Yb3+ doping concentrations. Luminescence decay curves of Pr3+:3P0 level were recorded as a function of the Yb3+ concentrations and energy transfer efficiency was also calculated. Based on Inokuti-Hirayama model, the energy transfer type from Pr3+ to Yb3+ was derived to be electric dipole-dipole interaction. ©, 2015, Chines Academy of Sciences. All right reserved.
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页码:751 / 756
页数:5
相关论文
共 17 条
[1]  
Trupke T., Green M.A., Wurfel P., Improving solar cell efficiencies by down-conversion of high-energy photons, J. Appl. Phys., 92, 3, pp. 1668-1674, (2002)
[2]  
Hua J.T., Chen B.J., Sun J.S., Et al., Color-tunable white-light emitting BaMg<sub>2</sub>Al<sub>6</sub>Si<sub>9</sub>O<sub>30</sub>:Eu<sup>2+</sup>, Tb<sup>3+</sup>, Mn<sup>2+</sup> phosphors via energy transfer, Chin. Opt., 5, 3, pp. 203-208, (2012)
[3]  
Jiang G.C., Wei X.T., Wang L.X., Preparationand luminescence of down-conversion material β-NaYF<sub>4</sub>:Tb<sup>3+</sup>, Yb<sup>3+</sup>, Spectrosc. Spect. Anal., 31, 2, pp. 331-334, (2011)
[4]  
Hua J.T., Chen B.J., Sun J.S., Et al., Introduction to up-conversion luminescence of rare earth doped materials, Chin. Opt., 3, 4, pp. 301-301, (2010)
[5]  
Vergeer P., Vlugt T.J.H., Kox M.H.F., Et al., Quantum cutting by cooperative energy transfer in Yb<sub>x</sub>Y<sub>1-</sub><sub>x</sub>PO<sub>4</sub>:Tb<sup>3+</sup>, Phys. Rev. B, 71, 1, (2005)
[6]  
Trupke T., Green M.A., Wurfel P., Improving solar cell efficiencies by up-conversion of sub-band-gap light, J. Appl. Phys., 92, 7, pp. 4117-4122, (2002)
[7]  
Chen X.P., Huang X.Y., Zhang Q.Y., Concentration-dependent near-infrared quantum cutting in NaYF<sub>4</sub>:Pr<sup>3+</sup>, Yb<sup>3+</sup> phosphor, J. Appl. Phys., 106, 6, (2009)
[8]  
Yang G.M., Zhou S.M., Lin H., Et al., Down-conversion near infrared emission in Pr<sup>3+</sup>, Yb<sup>3+</sup> co-doped Y<sub>2</sub>O<sub>3</sub> transparent ceramics, Physica B, 406, 19, pp. 3588-3591, (2011)
[9]  
Li K.Y., Wang R.Z., Qu M.H., Et al., Down-conversion materials preparation and the research of conversion efficiency in Pr<sup>3+</sup>, Yb<sup>3+</sup> co-doped YPO<sub>4</sub>, Chin. J. Lumin., 31, 5, pp. 486-491, (2010)
[10]  
Huang X.Y., Yu D.C., Zhang Q.Y., Enhanced near-infrared quantum cutting in GdBO<sub>3</sub>:Tb<sup>3+</sup>, Yb<sup>3+</sup> phosphors by Ce<sup>3+</sup> co-doping, J. Appl. Phys., 106, 11, (2009)