Phenolic carbon cloth-based electric double-layer capacitors with conductive interlayers and graphene coating

被引:21
作者
Lei, Chunhong [1 ,2 ]
Markoulidis, Foivos [1 ]
Wilson, Peter [1 ]
Lekakou, Constantina [1 ]
机构
[1] Univ Surrey, Fac Engn & Phys Sci, Dept Mech Engn Sci, Adv Mat Grp, Guildford GU2 7XH, Surrey, England
[2] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
关键词
Phenolic carbon cloth; Conductive interlayer; Graphene coating; Current collector; ACTIVATED CARBON; ENERGY DENSITY; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); SUPERCAPACITOR; COMPRESSION; FABRICS; PEDOT; RESIN;
D O I
10.1007/s10800-015-0909-x
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Phenolic resin-derived activated carbon (AC) cloths are used as electrodes for large-scale electric double-layer capacitors or supercapacitors. To increase the energy and power density of the supercapacitor, the contact resistance between the carbon cloth and the aluminium foil current collector is reduced by modifying the Al current collectors. Different modified Al current collectors, including Toyal-Carbo(A (R))(surface-modified Al), DAG(A (R)) (deflocculated Acheson (TM) graphite) coating and poly(3,4-ethylenedioxythiophene) (PEDOT) coating, have been tested and compared. The use of modified Al current collectors are shown to greatly reduce the contact resistance between the AC cloth and the Al foil. Another solution investigated in this study is to coat AC cloth with graphene through electrophoretic deposition (EPD). The graphene coated AC cloth is shown increased the capacitance and greatly reduced internal resistance.
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页码:251 / 258
页数:8
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