Conduction characteristics of N-Al codoping p-ZnO films by XPS
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Zhang, Zi-Cai
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Industrial and Commercial College, Hebei University, Baoding 071002, ChinaIndustrial and Commercial College, Hebei University, Baoding 071002, China
Zhang, Zi-Cai
[1
]
Yu, Wei
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College of Physics Science and Technology, Hebei University, Baoding 071002, ChinaIndustrial and Commercial College, Hebei University, Baoding 071002, China
Yu, Wei
[2
]
Zhang, Kun
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Industrial and Commercial College, Hebei University, Baoding 071002, ChinaIndustrial and Commercial College, Hebei University, Baoding 071002, China
Zhang, Kun
[1
]
Teng, Xiao-Yun
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College of Physics Science and Technology, Hebei University, Baoding 071002, ChinaIndustrial and Commercial College, Hebei University, Baoding 071002, China
Teng, Xiao-Yun
[2
]
Fu, Guang-Sheng
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College of Physics Science and Technology, Hebei University, Baoding 071002, ChinaIndustrial and Commercial College, Hebei University, Baoding 071002, China
Fu, Guang-Sheng
[2
]
机构:
[1] Industrial and Commercial College, Hebei University, Baoding 071002, China
[2] College of Physics Science and Technology, Hebei University, Baoding 071002, China
The ZnAlO:N films was prepared on α-Al2O3 substrates by the technique of helicon-wave-plasma assisted sputtering deposition. The as-grown ZnAlO:N film behaved n-type conduction at room temperature, but transformed into p-type conduction after annealed at 550°C in an O2 flow. The p-type ZnAlO:N film has a hole concentration of 2.1×1016 cm-3 and a Hall mobility of 5 cm2/V·s. X-ray photoelectron spectroscopy measurment indicated that substitution of N for O site is in forms of N atom (N)O and N molecule (N2)O for the ZnAlO:N films, and the conduction transition for the annealed ZnAlO:N film induced by the (N2)O donors decreased and the concentration of (N)O defect becomes dominant.