Preparation and performance of photocatalyst TiO2-Pt/CuS

被引:0
作者
Han, Yanhe [1 ]
Lu, Chenghao [1 ]
Cheng, Qi [1 ]
Liu, Chengqing [1 ]
Li, Yihan [1 ]
Chen, Jiaqing [1 ]
机构
[1] Department of Environmental Engineering, Beijing Institute of Petrochemical Technology, Beijing
来源
Gongneng Cailiao/Journal of Functional Materials | 2015年 / 46卷 / 09期
关键词
Composite semiconductor; CuS; Photocatalysis; TiO[!sub]2[!/sub;
D O I
10.3969/j.issn.1001-9731.2015.09.017
中图分类号
学科分类号
摘要
The TiO2/Pt and TiO2-Pt/CuS nano-crystalline photocatalystes were prepared by electrochemical deposition of Pt and chemical deposition of CuS on TiO2 nanotube array electrode fabricated using anodic oxidation method. Scanning electron microscope (SEM) and transmission electron microscopy (TEM) were used to characterize the morphology of TiO2, TiO2-Pt and TiO2-Pt/CuS. Energy dispersive spectrometer (EDS) was used to investigate the elemental structures of photocatalystes. The photocatalytic activities of the prepared samples were investigated by using photocatalytic degradation of H2O and organic compounds as model reactions in solution. The results showed that TiO2 nanotube array can maintain the original morphology under Pt electrochemical deposition and CuS chemical deposition. Pt can deposit in the TiO2 nanotube. Some CuS can form a mixed-phase with Pt on the surface of the TiO2 nanotube array electrode. The results obtained from the hydrolysis and the degradation of organic compounds showed that the order of photocatalytic activities of the prepared samples was TiO2-Pt/CuS>TiO2-Pt>TiO2. ©, 2015, Journal of Functional Materials. All right reserved.
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页码:09086 / 09091
页数:5
相关论文
共 19 条
[1]  
Fujishima A., Honda K., Electrochemical photolysis of water at a semiconductor electrode, Nature, 238, 5358, pp. 37-38, (1972)
[2]  
Li D., Zheng J., Chen X., Et al., Evaluation systems and materials for photocatalytic water splitting, Progress in Chemistry, 19, 4, pp. 464-477, (2007)
[3]  
Kudo A., Miseki Y., Heterogeneous photocatalyst materials for water splitting, Chem Soc Rev, 38, 1, pp. 253-278, (2009)
[4]  
Zhang J., Xu Q., Li C., Et al., Importance of the relationship between surface phases and photocatalytic activity of TiO<sub>2</sub>, Angew Chem Int Ed, 47, 9, pp. 1766-1769, (2008)
[5]  
Shi J.Y., Chen J., Li C., Et al., Photoluminescence characteristics of TiO<sub>2</sub> and their relationship to the photoassisted reaction of water/methanol mixture, J Phys Chem C, 111, 2, pp. 693-699, (2007)
[6]  
Kho Y.K., Iwase A., Rose A., Et al., Photocatalytic H<sub>2</sub> evolution over TiO<sub>2</sub> nanoparticles. The synergistic effect of anatase and rutile, J Phys Chem C, 114, 6, pp. 2821-2829, (2010)
[7]  
Kato H., Kudo A., New tantalate photocatalysts for water decomposition into H<sub>2</sub> and O<sub>2</sub>, Chem Phys Lett, 295, 5-6, pp. 487-492, (1998)
[8]  
Kato H., Kudo A., Highly efficient decomposition of pure water into H<sub>2</sub> and O<sub>2</sub> over NaTaO<sub>3</sub> photocatalysis, Catal Lett, 58, 2-3, pp. 153-154, (1999)
[9]  
Zhou C., Chen G., Li Y.X., Et al., Photocatalytic activities of Sr<sub>2</sub>Ta<sub>2</sub>O<sub>7</sub> nanosheets synthesized by a hydrothermal method, Int J Hydro Energ, 34, 5, pp. 2113-2120, (2009)
[10]  
Yan H.J., Yang J.H., Can L.I., Et al., Visible-light-driven hydrogen production with extremely high quantum efficiency on Pt-PdS/CdS photocatalyst, J Catal, 266, 2, pp. 165-168, (2009)