Refractive indices, densities and derived excess properties of binary and ternary systems with dimethyl sulfoxide, water and 1,4-dioxane

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作者
Omota, L.M. [1 ]
Iulian, O. [1 ]
Mateescu, C. [1 ]
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[1] Department of Applied Physical Chemistry and Electrochemistry, Faculty of Industrial Chemistry, University POLITEHNICA, 313, Splaiul Independentei, Bucharest 77206, Romania
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Density (specific gravity) - Distillation - Gas chromatography - Gravimetric analysis - Mixing - Numerical analysis - Organic compounds - Purification - Refractive index - Temperature - Water;
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摘要
Refractive indices and densities for binary dimethyl sulfoxide+water, dimethyl sulfoxide+1,4-dioxane systems and ternary dimethyl sulfoxide+water+1,4-dioxane system have been measured at 298.15 K, over the entire mole fraction scale of the mixture. Changes on molar volume, partial molar volume and molar refraction have been calculated. The experimental data were used to test several mixing rules for estimation of the refractive index.
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