Controllable synthesis and electrochemical performance of VO2(B) nanobelt arrays as cathode materials for sodium-ion batteries

被引:0
作者
Qin M.-L. [1 ]
Liu W.-M. [1 ]
Zhang Z.-C. [1 ]
Xu X.-X. [1 ]
机构
[1] School of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan
来源
Zhongguo Youse Jinshu Xuebao/Chinese Journal of Nonferrous Metals | 2018年 / 28卷 / 06期
关键词
Cathode material; Hydrothermal method; Nanobelt array; Sodium-ion battery; VO[!sub]2[!/sub](B);
D O I
10.19476/j.ysxb.1004.0609.2018.06.09
中图分类号
学科分类号
摘要
VO2(B) nanobelt arrays were synthesized by hydrothermal method with V2O5 as vanadium source and ethylene glycol as structure-directing agent and reductant, without using template. The crystal structure and morphology of synthesized VO2(B) were characterized by X-ray diffractometry (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The influences of ethylene glycol content and reaction time on structure and morphology of synthesized product were studied. As cathode materials for sodium-ion batteries, the effects of reaction time and charge-discharge voltage range on the electrochemical performance of synthesized VO2(B) were further researched. The results show that VO2(B) nanobelt arrays synthesized at 180 ℃ for 6 h using 10 mL ethylene glycol have better electrochemical performance in the voltage range of 1.5-4 V. © 2018, Science Press. All right reserved.
引用
收藏
页码:1151 / 1158
页数:7
相关论文
共 34 条
[1]  
Scrosati B., Garche J., Lithium batteries: Status, prospects and future, Journal of Power Sources, 195, 9, pp. 2419-2430, (2010)
[2]  
Manthiram A., Materials challenges and opportunities of lithium ion batteries, Journal of Physical Chemistry Letters, 2, pp. 176-184, (2011)
[3]  
Jeong G., Kim Y.U., Kim H., Kim Y.J., Sohn H.J., Prospective materials and applications for Li secondary batteries, Energy & Environmental Science, 4, 6, (2011)
[4]  
Etacheri V., Marom R., Elazari R., Salitra G., Aurbach D., Challenges in the development of advanced Li-ion batteries: A review, Energy & Environmental Science, 4, 9, (2011)
[5]  
Karden E., Ploumen S., Fricke B., Miller T., Snyder K., Energy storage devices for future hybrid electric vehicles, Journal of Power Sources, 168, 1, pp. 2-11, (2007)
[6]  
Yang T.-Z., Niu X.-Y., Qian T., Shen X.-W., Zhou J.-Q., Xu N., Yan C.-L., Half and full sodium-ion batteries based on maize with high-loading density and long-cycle life, Nanoscale, 8, 34, pp. 15497-15504, (2016)
[7]  
Jiang Y., Zhang H.-C., Yang H., Qi Z.-Y., Yu Y., Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub>@nitrogen, sulfur-codoped 3D porous carbon enabling ultra-long cycle life sodium-ion batteries, Nanoscale, 9, 18, pp. 6048-6055, (2017)
[8]  
Fang Y.-J., Chen Z.-X., Ai X.-P., Yang H.-X., Cao Y.-L., Recent developments in cathode materials for Na ion batteries, Acta Physico-Chimica Sinica, 33, 1, pp. 211-241, (2017)
[9]  
Yang S.-B., Dong W., Shen D., Li S.-N., Wang Z.-J., Zhang J.-M., Sun W., Zhang Q., Research progress of anode material for sodium-ion batteries, The Chinese Journal of Nonferrous Metals, 26, 5, pp. 1054-1064, (2016)
[10]  
Slater M.D., Kim D., Lee E., Johnson C.S., Sodium-ion batteries, Advanced Functional Materials, 23, 8, pp. 947-958, (2013)