Influence factors of sulfate attack on cement-based materials subjected to electrical pulse

被引:2
作者
Huang, Qian [1 ]
Wang, Chong [1 ]
Yang, Changhui [1 ]
Zhou, Limin [1 ]
Yin, Jiqiang [1 ]
机构
[1] College of Materials Science and Engineering, Chongqing University, Chongqing
来源
Dongnan Daxue Xuebao (Ziran Kexue Ban)/Journal of Southeast University (Natural Science Edition) | 2014年 / 44卷 / 05期
关键词
Acceleration; Cement-based materials; Electrical pulse; Influence factors; Sulfate attack;
D O I
10.3969/j.issn.1001-0505.2014.05.029
中图分类号
学科分类号
摘要
The effects of the water-cement ratio, types of attack solution and the period of pulse on sulfate attack on cement mortars subjected to electrical pulse were investigated through electrical pulse speeding up the migration of external sulfate ions into cement-based materials. The microstructures of the damaged specimens were examined by scanning electron microscope. The results show that for the mortars with the water-cement ratios of 0.3, 0.4 and 0.5, after immersion in the attack solution of Na2SO4 for 180 d, the flexural coefficients are 1.03, 0.98 and 0.94, respectively, and the compressive strength coefficients are 1.02, 0.96 and 0.90, respectively. However, after using electrical pulse for 30 d, the flexural coefficients are changed into 0.98, 0.95 and 0.90, respectively, and the compressive strength coefficients are 0.97, 0.96 and 0.91, respectively. A large amount of ettringite form in the damaged specimens, indicating that electrical pulse accelerates the erosion of cement-based mortars due to sulfate attack. When MgSO4 is used as the attack solution under electrical pulse, some calcium silicate hydrate (CSH) gel converts into non-cohesive magnesium silicate hydrate (MSH), resulting in greater strength loss of the specimens compared with that caused by sodium sulfate attack. Moreover, the deterioration degree of the specimens subjected to electrical pulse with the period of 10 s is greater than that with the period of 20 s.
引用
收藏
页码:1041 / 1045
页数:4
相关论文
共 11 条
[1]  
Kamile T.F., The effect of C<sub>3</sub>A content on sulfate durability of Portland limestone cement mortars , Construction and Building Materials, 36, pp. 437-447, (2012)
[2]  
Skaropoulou A., Kakail G., Tsivilis S., Thaumasite form of sulfate attack in limestone cement concrete: The effect of cement composition, sand type and exposure temperature , Construction and Building Materials, 36, pp. 527-533, (2012)
[3]  
Uysal M., Sumer M., Performance of self-compacting concrete containing different mineral admixtures , Construction and Building Materials, 25, 11, pp. 4112-4120, (2011)
[4]  
Zuo X., Sun W., Full process analysis of damage and failure of concrete subjected to external sulfate attack , Journal of the Chinese Ceramic Society, 37, 7, pp. 1063-1067, (2009)
[5]  
Castellote M., Andrade C., Alonso C., Measurement of the steady and non-steady-state chloride diffusion coefficients in a migration test by means of monitoring the conductivity in the anolyte chamber comparison with natural diffusion tests , Cement and Concrete Research, 31, 10, pp. 1411-1420, (2001)
[6]  
Yang C.C., Weng S.H., Effect of 95 degrees C temperature on the chloride-migration of concrete using electrical field, Materials Chemistry and Physics, 125, 3, pp. 876-882, (2011)
[7]  
Lorente S., Yssorche-Cubaynes M.P., Auger J., Sulfate transfer through concrete: migration and diffusion results , Cement and Concrete Composites, 33, 7, pp. 735-741, (2011)
[8]  
Wang C., Liu H., Luo Y., Et al., A preliminary research on accelerated test method of sulfate attack resistance of concrete based on electro-osmotic pulse , Journal of Tongji University: Natural Science, 41, 12, pp. 1865-1871, (2013)
[9]  
Al-Amoudi O.S.B., Sulfate attack and reinforcement corrosion in pain and blended cements exposed to sulfate environments , Building and Environment, 33, 1, pp. 53-61, (1998)
[10]  
Santhanam M., Cohen M.D., Olek J., Mechanism of sulfate attack: a fresh look: part 2. proposed mechanisms , Cement and Concrete Research, 33, 3, pp. 341-346, (2003)