Preparation and characterization of sodium-graphite intercalation compounds

被引：0

作者：

Akuzawa, Noboru ^{[1
]}

Yoshioka, Jun ^{[1
]}

Ozaki, Chihiro ^{[2
]}

Tokuda, Masahide ^{[2
]}

Ohkura, Kenji ^{[2
]}

Soneda, Yasushi ^{[3
]}

机构：

[1] Tokyo National College of Technology, 1220-2 Kunugida, Tokyo, Hachioji,193-0997, Japan

[2] SEC Corporation, 3-26 Osadano, Kyoto, Fukuchiyama,620-0853, Japan

[3] National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Ibaraki, Tsukuba,305-8569, Japan

来源：

Molecular Crystals and Liquid Crystals | 2002年 / 388卷 / 01期

关键词：

Alkali metal-graphite intercalation compounds - G-values - Metallic temperature dependence;

D O I：

10.1080/10587250215260

中图分类号：

学科分类号：

摘要：

Preparation and characterization of sodium-graphite intercalation compounds were investigated. It was confirmed that the resulting compound (NaC x) had the stage 8 structure with identity period of 2.8 nm. The Raman spectroscopy showed that the G-band signal of NaC x was observed at 1582 cm −1 and at 1608 cm −1, which is a typical indication of the formation of intercalation compounds. The g-value of NaC x was determined to be 2.0018 by the ESR measurement, which was very close to the reported values for the other alkali metal-graphite intercalation compounds. The electrical resistivity of NaC x was about 1/3 of that of host graphite at room temperature and showed metallic temperature dependence. © 2002, Copyright Taylor & Francis Group, LLC.

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页码：1 / 7

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