different dopant related to magnetic order and local structural changes in SrYCoO3 based compound

被引:0
作者
Sutjahja, Inge Magdalena [1 ]
Berthalita, Febri [1 ]
Nugroho, Agustinus Agung [1 ]
Tjia, May On [1 ]
机构
[1] Dept. of Physics, FMIPA, ITB, Jl. Ganesha 10, Bandung,40132, Indonesia
来源
UPB Scientific Bulletin, Series B: Chemistry and Materials Science | 2018年 / 80卷 / 02期
关键词
Perovskite - Spin dynamics - Antiferromagnetism - Zinc compounds - Iron compounds - Strontium compounds;
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摘要
A study is conducted on the relation between dopant induced changes in magnetic properties and local structural modifications in Sr0.775Y0.225(Co0.9Zn0.1)O3-. Temperature and field dependent magnetic responses of this compound are found to differ from those previously reported for Sr0.775Y0.225(Co0.9Fe0.1)O3-. The Fe-doped compound show near total suppression of FM, while Zn-doped compound retain measurable FM ordering. Local structures are shown to exhibit perceptible differences of Co-O bond lengths and Co-O-Co bond angles in the fully oxygenated octahedral layer. Those differences are argued to result in the different CF strengths that affect differently the Co3+ spin states and the inter-ionic magnetic interactions. © 2018 Politechnica University of Bucharest. All rights reserved.
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页码:135 / 148
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