Analyzing moisture self-diffusion coefficient and pore characteristics in Mongolian scots pine using single-sided NMR

In this study, single-sided nuclear magnetic resonance (NMR) spectroscopy was used to detect the changes of axial and radial tangential moisture self-diffusion coefficient with diffusion time of Mongolian Scots pine (Pinus sylvestris var. mongolica). The result shows that, the self-diffusion coefficient values ranked as axial > radial > tangential. The axial self-diffusion coefficient exhibited free diffusion, averaging 2.0 x 10(-9) m(2)/s, while radial and tangential directions showed restricted diffusion, decreasing with time. Based on the restricted diffusion theory, the results are as follows, radial and tangential tracheid surface-to-volume ratios (S/V) were approximately 203,000 +/- 10,600/m and 265,000 +/- 25,000/m, average size of lumen ends and pits 6.4 +/- 0.33 mu m and 6.2 +/- 0.49 mu m in radial and tangential direction respectively, tortuosity values tau(R) = 3.96 +/- 0.02 and tau(T) = 6.59 +/- 0.45. Combining S/V with the form factor (Fs) and the T-2 relaxation mechanism yields the following results, average pore sizes for radial and tangential tracheids were 19.7 +/- 1.44 mu m and 15.09 +/- 1.3 mu m, cell water transverse surface relaxation rates were rho(2R) = 0.103 +/- 0.005 mu m/ms and rho(2T) = 0.082 +/- 0.007 mu m/ms. The pore size obtained above is within an acceptable range with the results of SEM. This study provides a systematic method for wood moisture self-diffusion analysis.