Let an n x n complex matrix Abe such that I+A is invertible. The Cayley transform of A, denoted by C(A), is defined as C(A) = (I + A)-1(I -1 (I - A). Fallat and Tsatsomeros (2002) [5] and Mondal et al. (2024) [15] studied the Cayley transform of a matrix Ain the context of P-matrices, H-matrices, M-matrices, totally positive matrices, positive definite matrices, almost skew-Hermitian matrices, and semipositive matrices. In this paper, the investigation of the Cayley transform is continued for Toeplitz matrices, circulant matrices, unipotent matrices, and dual matrices. An expression of the Cayley transform for dual matrices is established. It is shown that the Cayley transform of a dual symmetric matrix is always a dual symmetric matrix. The Cayley transform of a dual skew-symmetric matrix is discussed. The results are illustrated with examples. (c) 2024 Elsevier Inc. All rights are reserved, including those for text and data mining, AI training, and similar technologies.