Application of magnetic-graphene oxide/poly(allylamine hydrochloride) microcapsules for adsorption of dyes

被引:0
作者
Zhao Z. [1 ,2 ]
Li Q. [1 ,2 ]
Sun Y. [1 ,2 ]
Gong J. [1 ,2 ]
Li Z. [1 ,2 ]
Zhang J. [1 ,2 ,3 ]
机构
[1] School of Textile Science and Engineering, Tiangong University, Tianjin
[2] Key Laboratory of Advanced Textile Composites, Ministry of Education, Tiangong University, Tianjin
[3] Collaborative Innovation Center for Eco-Textiles of Shandong Province, Qingdao, 266071, Shandong
来源
Fangzhi Xuebao/Journal of Textile Research | 2020年 / 41卷 / 07期
关键词
Adsorption; Dyeing wastewater; Graphene oxide; Magnetic microcapsules; Methylene blue;
D O I
10.13475/j.fzxb.20190903908
中图分类号
学科分类号
摘要
Facing the problem that printing and dyeing wastewater pollutes environment, this paper reports on hybrid magnetic microcapsules with Fe3O4-graphene oxide (Fe3O4-GO) and poly(allylamine hydrochloride) (PAH) for purifying and cleaning the wastewater during dyeing processes. These microcapsules were made through layer-by-layer (LBL) self-assembly due to the opposite charges of Fe3O4-GO and PAH. The structure and morphology of Fe3O4-GO and (PAH/Fe3O4-GO)n were characterized. Cationic methylene blue was then used to study the adsorption behaviour and mechanism of magnetic microcapsules. When methylene blue dye (0.2-3.0 mg/mL) was absorbed for 20 minutes by microcapsules, the adsorption reached maximum. Moreover, the absorption reaches maximum value at pH of 12 with an adsorption rate of 96.5%. The pseudo-second-order adsorption kinetic and Langmuir adsorption isothermal model are more suitable for describing the adsorption process of methylene blue on magnetic (PAH/Fe3O4-GO)2 microcapsules, with the theoretical maximum adsorption of 219.996 mg/g. Copyright No content may be reproduced or abridged without authorization.
引用
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页码:109 / 116
页数:7
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