Investigations on selective flotation separation of quartz from hematite using novel solubility amine as collector: experimental and simulation

被引:0
作者
Liu, Wenbao [1 ,2 ]
Wang, Bohan [1 ]
Zhao, Qiang [1 ]
Mao, Yong [1 ]
Liu, Wengang [1 ]
Shen, Yanbai [1 ]
机构
[1] School of Resources and Civil Engineering, Northeastern University, Shenyang
[2] Guizhou Academy of Sciences, Guizhou, Guiyang
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Hematite; Hydroxy cationic collector; Interaction mechanism; Quartz; Reverse flotation;
D O I
10.1016/j.molliq.2024.126084
中图分类号
学科分类号
摘要
Traditional cationic collectors usually have some disadvantages, such as poor selectivity and limited water solubility, which negatively impact flotation efficiency. Thus, a novel cationic collector, 2-(dodecylamino)-2-methyl-1-propanol (DAMP) was developed to enhance the separation efficiency of hematite and quartz. The flotation behavior of DAMP was systematically investigated, and the results indicated that DAMP had good flotation performance and excellent selectivity. Optimal flotation separation of mixed hematite and quartz achieved a concentrate with a TFe grade of 67.79 % and a recovery rate of 91.26 % at a pulp pH of 7.34, using 4.0 mg/L starch and 20.0 mg/L DAMP. Furthermore, the interaction mechanisms between DAMP and the minerals were explored using zeta potential measurements, Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and molecular dynamics (MD) simulation. The findings confirmed that DAMP exhibited superior selectivity compared to DDA, and the adsorption of DAMP on minerals occurred through electrostatic forces and hydrogen bonding interactions. © 2024 Elsevier B.V.
引用
收藏
相关论文
共 41 条
[1]  
Liu W., Liu W., Dai S., Yang T., Li Z., Fang P., Enhancing the purity of magnesite ore powder using an ethanolamine-based collector: insights from experiment and theory, J. Mol. Liq., 268, pp. 215-222, (2018)
[2]  
Li R., Luo X., Wen S., Li C., Wei D., Yang W., Zhang Y., Zhu Y., Wang Y., Three-phase froth stability in hematite flotation using DDA as a collector, Miner. Eng., 195, (2023)
[3]  
Sahoo H., Sinha N., Rath S.S., Das B., Ionic liquids as novel quartz collectors: insights from experiments and theory, Chem. Eng. J., 273, pp. 46-54, (2015)
[4]  
Tao D., Recent advances in fundamentals and applications of nanobubble enhanced froth flotation: a review, Miner. Eng., 183, (2022)
[5]  
Araujo A.C., Viana P.R.M., Peres A.E.C., Reagents in iron ores flotation, Miner. Eng., 18, pp. 219-224, (2005)
[6]  
Liu W., Liu W., Wang X., Wei D., Wang B., Utilization of novel surfactant N-dodecyl-isopropanolamine as collector for efficient separation of quartz from hematite, Sep. Purif. Technol., 162, pp. 188-194, (2016)
[7]  
Mowla D., Karimi G., Ostadnezhad K., Removal of hematite from silica sand ore by reverse flotation technique, Sep. Purif. Technol., 58, pp. 419-423, (2008)
[8]  
Zhang M., Xu Z., Zhang Q., Dan Z., Fu H., Yao W., Properties and potential application of ozone-oxidized starch for enhanced reverse flotation of fine hematite, Miner. Eng., 198, (2023)
[9]  
Yang S., Xu Y., Kang H., Li K., Li C., Investigation into starch adsorption on hematite and quartz in flotation: role of starch molecular structure, Appl. Surf. Sci., 623, (2023)
[10]  
Weng X., Mei G., Zhao T., Zhu Y., Utilization of novel ester-containing quaternary ammonium surfactant as cationic collector for iron ore flotation, Sep. Purif. Technol., 103, pp. 187-194, (2013)