Determination of Dibutyl phthalate with THz time-domain spectroscopy

被引：0
|
作者：
Zhao, Lijun [1 ]
Gao, Lei [1 ]
Jiang, Chen [1 ]
Yi, Lingxue [1 ]
Yu, Xianshu [1 ]
Zhao, Kun [1 ]
机构：
[1] Beijing Key Laboratory of Optical Detection Technology for Oil and Gas, China University of Petroleum, Beijing
来源：
Guangxue Xuebao/Acta Optica Sinica | 2015年 / 35卷
关键词：
Absorption coeffcient; Dibutyl phthalate; Refractive index; Terahertz time-domain spectroscopy;
D O I：
10.3788/AOS201535.s130001
中图分类号：
学科分类号：
摘要：
This paper adopts terahertz time-domain spectroscopy to identify dibutyl phthalate(DBP), one kind of industrial plasticizer. Terahertz time-domain spectroscopy techniques are used to obtain time-domain spectroscopy(0.2~1.5 THz) of different DBP concentrations in ethyl alcohol and n-hexane at room temperature in nitrogen atmosphere. Optical parameters calculation results show that refractive index, absorption coefficient and other optical parameters in 0.2~1.5 THz band of DBP/n-hexane and DBP/Ethyl alcohol solutions correspond with concentrations. According to the absorption coefficient, refractive index and correlations between frequency-domain spectroscopy of area and concentration, it can be obtained content of DBP in any unknown solutions. The results could help to provide a new way and new method to identify phthalate acid esters (PAEs) in white spirit or other soft drinks. ©, 2015, Chinese Optical Society. All right reserved.
引用
收藏
页数：7
相关论文
共 23 条
  • [1] Jackson J., Sutton R., Sources of endocrine-disrupting chemicals in urban wastewater, Oakland, CA, Science of the Total Environment, 405, 1-3, pp. 153-160, (2008)
  • [2] Field K.G., Chern E.C., Dick L.K., Et al., A comparative study of cultureindependent, libraryindependent genotypic methods of fecal source tracking, Water Health, 1, 4, pp. 181-194, (2003)
  • [3] Bjorklund K., Cousins A.P., Stromvall A., Et al., Phthalates and nonyl-phenols in urban runoff: Occurrence, distribution and area emission factors, Science of the Total Environment, 407, 16, pp. 4665-4672, (2009)
  • [4] Chai L., Xin Z., Cai J., Et al., Determination of phthalate plasticizers in foods, Food Science, 29, 7, pp. 362-365, (2008)
  • [5] Lu Y., Hu X., Fang H., Et al., Determination of 4 phthalates in plastic bottled edible oil by gel permeation chromatography and gas chromatography/mass spectrometry, Cereals & Oils, 11, pp. 31-38, (2008)
  • [6] Yang Y., Mu Q., Yan D., Determination of phthalates by gas chromatography, Chemical Research, 21, 5, pp. 48-50, (2010)
  • [7] Zhang L., Chen H., Li J., Et al., Recent progress of methods for detection of phthalate esters, Physical Testing and Chemical Analysis, 47, 2, pp. 241-246, (2011)
  • [8] Chen L., Yao Y., Wang H., Et al., HPLC determination of phthalates in cosmetics, Physical Testing and Chemical Analysis, 21, 5, pp. 48-50, (2010)
  • [9] Jen J.F., Determination of the phthalate esters from food contacted mate-rials by on-line microdialysis and liquid chromatography, Journal of Chromatography A, 1130, 1, pp. 28-30, (2006)
  • [10] Lou J., Determination of phthalate esters in plastic tablecloth by accelerated solvent extraction and gas chromatography-mass spectrometry, Chemical Research, 22, 2, pp. 65-67, (2011)
123