Pincer-plus-one ligands in self-assembly with palladium(II): a molecular square and a molecular tetrahedron

被引:8
作者
Behnia, Ava [1 ]
Boyle, Paul D. [1 ]
Fard, Mahmood A. [1 ]
Blacquiere, Johanna M. [1 ]
Puddephatt, Richard J. [1 ]
机构
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
COORDINATION-COMPLEXES; METALLOMACROCYCLES;
D O I
10.1039/c6dt04264c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The combination of a palladium(II) precursor with a diimine-phenol ligand and an oxidant (H2O2 or O-2) under different conditions has, serendipitously, given both a molecular square and a molecular tetrahedron by self-assembly of building blocks comprising palladium(II) centres coordinated to the oxidised forms of the ligand.
引用
收藏
页码:19485 / 19490
页数:6
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