Experimental study on simultaneous desulfurization and denitrification with ammonia in WFGD system combined with plasma oxidation of NO

被引:1
作者
Zhang, Jubing [1 ,2 ]
Zhou, Ying [3 ]
Zhong, Zhaoping [2 ]
Jiang, Xiaoxiang [1 ]
Piao, Guilin [1 ]
机构
[1] Engineering Laboratory for Energy System Process Conversion and Emission Control Technology of Jiangsu Province, Nanjing Normal University, Nanjing
[2] Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing
[3] Nanjing Yuanheng Environmental Research Institute Co., Ltd, Nanjing
来源
Dongnan Daxue Xuebao (Ziran Kexue Ban)/Journal of Southeast University (Natural Science Edition) | 2014年 / 44卷 / 06期
关键词
NO oxidation; Plasmas; Simultaneous desulfurization and denitrification; Wet ammonia desulfurization;
D O I
10.3969/j.issn.1001-0505.2014.06.018
中图分类号
学科分类号
摘要
To increase the NOx removal efficiency in simultaneous desulfurization and denitrification of flue gas, the plasma oxidation technology was applied to the wet flue gas desulfurization (WFGD) process. The testing apparatus for simultaneous desulfurization and denitrification with ammonia in WFGD system combined with plasma oxidation of NO was established. The effects of liquid-gas ratio, ammonia concentration, flue gas flow rate, flue gas temperature, NO initial concentration and SO2 initial concentration on the removal efficiency of SO2 and NOx were investigated. The results show that higher liquid-gas ratio, higher ammonia concentration, lower gas flow rate, lower flue gas temperature, lower NO initial concentration and lower SO2 initial concentration contribute to higher NOx removal efficiency, while the SO2 removal efficiency remains almost the same under corresponding experimental parameters. The removal efficiency of SO2 and NOx reach 99.6% and 69.4%, respectively, under the following conditions: liquid-gas ratio of 10 L/m3; ammonia concentration of 4 mol/L; flue gas flow rate of 10 m3/h; flue gas temperature of 85℃; NO initial concentration of 3.5×10-4; SO2 initial concentration of 1.0×10-3. ©, 2014, Dongnan Daxue Xuebao (Ziran Kexue Ban)/Journal of Southeast University (Natural Science Edition). All right reserved.
引用
收藏
页码:1194 / 1199
页数:5
相关论文
共 16 条
  • [1] Gao H., Qin H., Guo J., Discussion on the wet flue gas desulphurization and denitrification technology for coal-fired industrial boiler gas, Industrial Safety and Environmental Protection, 40, 5, pp. 12-15, (2014)
  • [2] Zhao N., Lu R., Present situation and prospect of flue gas simultaneous desulfurization and denitrification, China Resources Comprehensive Utilization, 29, 10, pp. 31-33, (2011)
  • [3] Liang Z.W., Xu H.L., Wang Y.L., Et al., An investigation of a process for partial nitrification and autotrophic denitrification combined desulfurization in a single biofilm reactor, Biodegradation, 24, 6, pp. 843-853, (2013)
  • [4] Xie H.W., Zhang Y., Fuzzy synthetic evaluation of flue gas simultaneous desulfurization and denitrification technology, Advanced Materials Research, 726, pp. 3943-3946, (2013)
  • [5] Zhao Y., Guo T.X., Chen Z.Y., Experimental study on simultaneous desulfurization and denitrification from flue gas with composite absorbent, Environ Prog Sustain, 30, 2, pp. 216-220, (2011)
  • [6] Zhao Y., Han Y.H., Ma T.Z., Et al., Simultaneous desulfurization and denitrification from flue gas by ferrate (VI), Environ Sci Technol, 45, 9, pp. 4060-4065, (2011)
  • [7] Kuropka J., Simultaneous desulphurization and denitrification of flue gases, Environment Protection Engineering, 34, 4, pp. 187-195, (2008)
  • [8] Wei Z.S., Lin Z.H., Niu H.J., Et al., Simultaneous desulfurization and denitrification by microwave reactor with ammonium bicarbonate and zeolite, J Hazard Mater, 162, 2, pp. 837-841, (2009)
  • [9] Huang L.W., Dang Y.X., Removal of SO<sub>2</sub> and NO<sub>x</sub> by pulsed corona combined with in situ Ca(OH)<sub>2</sub> absorption , Chinese Journal of Chemical Engineering, 19, 3, pp. 518-522, (2011)
  • [10] Jia Y., Du D.Q., Zhang X.X., Et al., Simultaneous removal of SO<sub>2</sub> and NO<sub>x</sub> with ammonia absorbent in a packed column, Korean J Chem Eng, 30, 9, pp. 1735-1740, (2013)