Preparation of spherical activated carbon from alkali lignin

被引:0
作者
College of Material Science and Engineering, Northeast Forestry University, Harbin, China [1 ]
机构
[1] College of Material Science and Engineering, Northeast Forestry University, Harbin
来源
Chem. Ind. For. Prod. | / 1卷 / 16-22期
关键词
Activate; Activated carbon; Spherical; Straw alkali lignin;
D O I
10.3969/j.issn.0253-2417.2015.01.003
中图分类号
学科分类号
摘要
Spherical activated carbon was prepared from the industrial alkali lignin via three steps: preparation of spherical lignin precursor, carbonization, and activation. Effects of preparation and activitation conditions of spherical lignin precursor on its morphology and particle size of the spherical activated carbon were investigated. SEM, N2(77K) adsorption-desorption isotherm, and FT-IR were used for characterizing its morphology structure, adsorption property, and surface functional groups, respectively. The results showed that spherical lignin precursor with diameter of approximate 5 μm could be obtained under the reaction temperature 90℃, stirring rate 200 r/min, reaction time 10 h, and pH 3.0. After carbonization at 300℃ followed by activation at 850℃, spherical activated carbon with BET surface area of 776.96 m2/g, total pore volume of 0.487 1 cm3/g, and average pore diameter of 2.51 mm could be obtained. ©, 2015, Editorial Board of Chemistry and Industry of Forest Products. All right reserved.
引用
收藏
页码:16 / 22
页数:6
相关论文
共 15 条
  • [1] Baccara R., Bouzid J., Feki M., Et al., Preparation of activated carbon from Tunisian olive-waste cakes and its application for adsorption of heavy metal ions, Journal of Hazardous Materials, 162, 2-3, pp. 1522-1529, (2009)
  • [2] Sun N.-N., Sun C.-G., Liu H., Et al., Synthesis, characterization and evaluation of activated spherical carbon materials for CO<sub>2</sub> capture, Fuel, 113, pp. 854-862, (2013)
  • [3] Carrott P.J.M., Mourao P.A.M., Carrott M.M.L.R., Controlling the micropore size of activated carbons for the treatment of fuels and combustion gases, Applied Surface Science, 252, 17, pp. 5953-5956, (2006)
  • [4] Shi Q.-Q., Zhang J., Zhang C.-L., Et al., Preparation of activated carbon from cattail and its application for dyes removal, Journal of Environmental Sciences, 22, 1, pp. 91-97, (2010)
  • [5] Merdy P., Guillon E., Aplincourt M., Et al., Copper sorption on a straw lignin: Experiments and Epr characterization, Journal of Colloid and Interface Science, 245, 1, pp. 24-31, (2002)
  • [6] Wang Q., Liang X.-Y., Qiao W.-M., Et al., Preparation of polystyrene-based activated carbon spheres with high surface area and their adsorption to dibenzothiophene, Fuel Processing Technology, 90, 3, pp. 381-387, (2009)
  • [7] Zhang X., Liang X.-Y., Huo S.-M., Et al., Preparation and adsorption of CO<sub>2</sub> of phenolic resin-based spherical activated carbon, Journal of Materials Science & Engineering, 28, 5, pp. 705-710, (2010)
  • [8] Liu X.-J., Wang Y.-B., Qiao W.-M., Et al., Preparation of pitch-based spherical activated carbons by ZnCl<sub>2</sub>, Journal of East China University of Science and Technology: Natural Science Edition, 36, 4, pp. 523-528, (2010)
  • [9] Romero-Anaya A.J., Lillo-Rodenas M.A., Linares-Solano A., Spherical activated carbons for low concentration toluene adsorption, Carbon, 48, 9, pp. 2625-2633, (2010)
  • [10] Liu M.-H., Chen G.-F., Yao M.-B., Et al., The adsorption performance of L-lysine on a spherical lignin adsorbent, Transactions of China Pulp and Paper, 24, 1, pp. 72-75, (2009)