Measurement of crystallinity and crystal orientation of polyester industrial yarns by 2-D X-ray diffraction

被引:0
作者
Ge C. [1 ]
Lü W. [1 ]
Shi J. [2 ]
Xu T. [1 ]
Chen S. [1 ]
Li N. [1 ]
Chen W. [1 ]
机构
[1] National Engineering Lab for Textile Fiber Materials and Processing Technology, Zhejiang Sci-Tech University, Hangzhou, 310018, Zhejiang
[2] Zhejiang Guxiandao Industrial Fiber Co., Ltd., Shaoxing, 312000, Zhejiang
来源
Fangzhi Xuebao/Journal of Textile Research | 2018年 / 39卷 / 03期
关键词
2-D X-ray diffraction; Crystallinity; Orientation; Polyester industrial yarn;
D O I
10.13475/j.fzxb.20170600807
中图分类号
学科分类号
摘要
In order to establish the relationship between the microstructure and mechanical properties of polyester industrial yarns, it is very important to develop an effective test method. Two-dimensional X-ray diffraction method was used to study the crystallinity, crystal orientation and its relationship with the properties of polyester industrial yarns, including high tenacity type (HT), low shrinkage type (LS) and super low shrinkage type (SLS). The results show that the SLS with maximal crystallinity, maximal grain size and minimum orientation is the smallest in dry heat shrinkage ratio and the best in dimension stability. Additionally, the largest breaking strength and the minimum elongation at break of the HT are ascribed to its minimum crystallinity, minimum grain size and maximal orientation. Accordingly, it can be concluded that the crystallinity and grain size mainly influence the dry heat shrinkage ratio of polyester industrial yarns, and the crystal orientation mainly influence the breaking strength, elongation at break and elastic modulus of the fibers. Copyright No content may be reproduced or abridged without authorization.
引用
收藏
页码:19 / 25
页数:6
相关论文
共 16 条
  • [1] Scheir J., Long T.E., Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters, pp. 31-104, (2003)
  • [2] Wang Y., Development situation and application of polyester technical yarn industry, Synthetic Fiber in China, 40, 10, pp. 1-5, (2011)
  • [3] Demirel B., Yaras A., Elcicek H., Crystallization behavior of PET materials, Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 13, 1, pp. 26-35, (2016)
  • [4] Yilmazer U., Xanthos M., Bayram G., Et al., Viscoelastic characteristics of chain extended/branched and linear polyethylene terephthalate resins, Journal of Applied Polymer Science, 75, 11, pp. 1371-1377, (2000)
  • [5] Zhao X., Lin L., Yu Z., Et al., A XRD method to measure orientation of single crystal superalloys, Rare Metal Materials & Engineering, 38, 7, pp. 1280-1283, (2009)
  • [6] Canetti M., Bertini F., Crystalline and supermolecular structure evolution of poly (ethylene terephthalate) during isothermal crystallization and annealing treatment by means of wide and small angle X-ray investigations, European Polymer Journal, 46, 2, pp. 270-276, (2010)
  • [7] Haubruge H.G., Jonas A.M., Legras R., Morphological study of melt-crystallized poly (ethylene terephthalate): a comparison of transmission electron microscopy and small-angle X-ray scattering of bulk samples, Macromolecules, 37, 1, pp. 126-134, (2004)
  • [8] Liu Y., Yin L., Zhao H., Et al., Insights into process-structure-property relationships of poly (ethylene terephthalate) industrial yarns by synchrotron radiation WAXD and SAXS, Journal of Applied Polymer Science, 132, 36, (2015)
  • [9] Zhu Y., Chen X., Discussion on crystallinity calculated by the technology of peak separation, Research and Exploration in Laboratory, 3, 29, pp. 42-43, (2010)
  • [10] Zhu Y., Cao Q., Chen X., Et al., Study on crystallinity and degree of orientation of naturally colored cottons, Journal of Donghua University(Natural Science Edition), 35, 6, pp. 626-631, (2009)