CoFe2O4 nanoparticle embedded carbon nanofibers: A promising non-noble metal catalyst for oxygen evolution reaction

被引:3
作者
Kamble, T. P. [1 ]
Shingte, S. R. [2 ]
Chavan, V. D. [3 ]
Kim, Deok-Kee [3 ]
Mujawar, S. H. [4 ]
Dongale, T. D. [1 ]
Patil, P. B. [2 ]
机构
[1] Shivaji Univ, Sch Nanosci & Technol, Kolhapur 416004, Maharashtra, India
[2] Shivaji Univ, New Coll, Dept Phys, Kolhapur 416012, Maharashtra, India
[3] Sejong Univ, Dept Elect Engn & Convergence Engn Intelligent Dro, Seoul, South Korea
[4] Yashawantrao Chavan Inst Sci, Dept Phys, Satara 415001, Maharashtra, India
基金
新加坡国家研究基金会;
关键词
MOF; Nanofibers; Cobalt ferrite; Non noble metal catalyst; Oxygen evolution reaction; ELECTROCATALYTIC PERFORMANCE; MFE2O4; M; OXIDATION; HYDROGEN; GRAPHENE; OXIDE; SIZE; NI; CO; CU;
D O I
10.1016/j.ijhydene.2024.10.353
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
There is a strong demand for noble metal-free durable catalysts to facilitate the advancement of clean, sustainable energy technologies and to replace energy equipment reliant on fossil fuels. In this study, metal-organic framework (MOF)-derived CoFe2O4 (CFO) nanoparticle-embedded electrospun carbon nanofibers (CNFs) were synthesized. Nanofibers were calcined at three different temperatures to obtain optimum electrocatalytic performance in oxygen evolution reaction (OER). Nanofibers annealed at 800 degrees C (CFO@CNFs 800) displayed a reduced overpotential of 300 mV while maintaining a steady current density of 10 mA cm- 2. CFO@CNFs 800 demonstrated Tafel slope 42 mV dec- 1 with excellent long-term stability up to 48 h. The synergistic effect of the redox activity of CFO coupled with the high surface area and conductivity of carbon nanofibers is responsible for enhanced OER performance.
引用
收藏
页码:1099 / 1107
页数:9
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