CoFe2O4 nanoparticle embedded carbon nanofibers: A promising non-noble metal catalyst for oxygen evolution reaction

被引:4
作者
Kamble, T. P. [1 ]
Shingte, S. R. [2 ]
Chavan, V. D. [3 ]
Kim, Deok-Kee [3 ]
Mujawar, S. H. [4 ]
Dongale, T. D. [1 ]
Patil, P. B. [2 ]
机构
[1] Shivaji Univ, Sch Nanosci & Technol, Kolhapur 416004, Maharashtra, India
[2] Shivaji Univ, New Coll, Dept Phys, Kolhapur 416012, Maharashtra, India
[3] Sejong Univ, Dept Elect Engn & Convergence Engn Intelligent Dro, Seoul, South Korea
[4] Yashawantrao Chavan Inst Sci, Dept Phys, Satara 415001, Maharashtra, India
基金
新加坡国家研究基金会;
关键词
MOF; Nanofibers; Cobalt ferrite; Non noble metal catalyst; Oxygen evolution reaction; ELECTROCATALYTIC PERFORMANCE; MFE2O4; M; OXIDATION; HYDROGEN; GRAPHENE; OXIDE; SIZE; NI; CO; CU;
D O I
10.1016/j.ijhydene.2024.10.353
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
There is a strong demand for noble metal-free durable catalysts to facilitate the advancement of clean, sustainable energy technologies and to replace energy equipment reliant on fossil fuels. In this study, metal-organic framework (MOF)-derived CoFe2O4 (CFO) nanoparticle-embedded electrospun carbon nanofibers (CNFs) were synthesized. Nanofibers were calcined at three different temperatures to obtain optimum electrocatalytic performance in oxygen evolution reaction (OER). Nanofibers annealed at 800 degrees C (CFO@CNFs 800) displayed a reduced overpotential of 300 mV while maintaining a steady current density of 10 mA cm- 2. CFO@CNFs 800 demonstrated Tafel slope 42 mV dec- 1 with excellent long-term stability up to 48 h. The synergistic effect of the redox activity of CFO coupled with the high surface area and conductivity of carbon nanofibers is responsible for enhanced OER performance.
引用
收藏
页码:1099 / 1107
页数:9
相关论文
共 38 条
[21]   Metal-Organic Framework Derived Hybrid Co3O4-Carbon Porous Nanowire Arrays as Reversible Oxygen Evolution Electrodes [J].
Ma, Tian Yi ;
Dai, Sheng ;
Jaroniec, Mietek ;
Qiao, Shi Zhang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (39) :13925-13931
[22]   Effect of annealing temperature on morphologies of metal organic framework derived NiFe2O4 for supercapacitor application [J].
Patil, P. D. ;
Shingte, S. R. ;
Karade, V. C. ;
Kim, J. H. ;
Dongale, T. D. ;
Mujawar, S. H. ;
Patil, A. M. ;
Patil, P. B. .
JOURNAL OF ENERGY STORAGE, 2021, 40
[23]   Confined Transformation of Organometal-Encapsulated MOFs into Spinel CoFe2O4/C Nanocubes for Low-Temperature Catalytic Oxidation [J].
Qin, Lei ;
Xu, Zehai ;
Zheng, Yilian ;
Li, Chang ;
Mao, Jingwen ;
Zhang, Guoliang .
ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (14)
[24]   Insights of enhanced oxygen evolution reaction of nanostructured cobalt ferrite surface [J].
Rana, Supriya ;
Yadav, Krishna K. ;
Guchhait, Sujit Kumar ;
Nishanthi, S. T. ;
Mehta, S. K. ;
Jha, Menaka .
JOURNAL OF MATERIALS SCIENCE, 2021, 56 (14) :8383-8395
[25]   Zn-substituted MnCo2O4 nanostructure anchored over rGO for boosting the electrocatalytic performance towards methanol oxidation and oxygen evolution reaction (OER) [J].
Rebekah, A. ;
Anantharaj, Sengeni ;
Viswanthan, C. ;
Ponpandian, N. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (29) :14713-14727
[26]   Development of MOF-Derived Carbon-Based Nanomaterials for Efficient Catalysis [J].
Shen, Kui ;
Chen, Xiaodong ;
Chen, Junying ;
Li, Yingwei .
ACS CATALYSIS, 2016, 6 (09) :5887-5903
[27]   Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion [J].
Shinagawa, Tatsuya ;
Garcia-Esparza, Angel T. ;
Takanabe, Kazuhiro .
SCIENTIFIC REPORTS, 2015, 5
[28]   1D hollow MFe2O4 (M = Cu, Co, Ni) fibers by Solution Blow Spinning for oxygen evolution reaction [J].
Silva, Vinicius D. ;
Ferreira, Luciena S. ;
Simoes, Thiago A. ;
Medeiros, Eliton S. ;
Macedo, Daniel A. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 540 :59-65
[29]   Pseudocapacitive Li+ storage boosts ultrahigh rate performance of structure-tailored CoFe2O4@Fe2O3 hollow spheres triggered by engineered surface and near-surface reactions [J].
Sun, Baoyu ;
Lou, Shuaifeng ;
Qian, Zhengyi ;
Zuo, Pengjian ;
Du, Chunyu ;
Ma, Yulin ;
Huo, Hua ;
Xie, Jingying ;
Wang, Jiajun ;
Yin, Geping .
NANO ENERGY, 2019, 66
[30]   Best Practices for Reporting Electrocatalytic Performance of Nanomaterials [J].
Voiry, Damien ;
Chhowalla, Manish ;
Gogotsi, Yury ;
Kotov, Nicholas A. ;
Li, Yan ;
Penner, Reginald M. ;
Schaak, Raymond E. ;
Weiss, Paul S. .
ACS NANO, 2018, 12 (10) :9635-9638