Effects of superabsorbent polymer and natural zeolite on shrinkage, mechanical properties, and porosity in ultra-high performance concretes

The low water-to-binder ratio of ultra-high performance concrete (UHPC) often causes shrinkage and cracking due to early-age self-desiccation. This leads to significant initial dimensional instability, which may compromise structural integrity. As a promising solution, internal curing agents such as superabsorbent polymers (SAP) and natural zeolite have the potential to mitigate shrinkage and achieve self-stressing properties. This research aims to provide a comprehensive comparison between SAP and zeolite's effects within a consistent UHPC formulation. Six UHPC mixtures (including the reference mixture) were designed: three with SAP dosages of 0.2%, 0.4%, and 0.6% by cement mass, and two with zeolite replacing silica fume at 25% and 50% by mass. Various testing methods, including autogenous and drying shrinkage assessment, heat of hydration and thermogravimetric analysis, compressive strength evaluation, mercury intrusion porosimetry (MIP), nuclear magnetic resonance (NMR), were employed to assess the mixtures at different stages of curing. The result reveals that the incorporation of SAP and zeolite in the mixtures significantly reduces UHPC's early-age autogenous shrinkage. Moreover, SAP and zeolite additions impact mechanical properties, demonstrating that a balance between shrinkage control and compressive strength can be reached, through an optimization of the additions to achieve the desired performance. Microstructural analysis through MIP and NMR reveals increased overall porosity of the UHPC with SAP and zeolite, suggesting that low-field NMR can be a valuable tool for complementing conventional test methods. The outcome of this study provided valuable insights into optimizing the balance between durability and mechanical performance, paving the way for more sustainable and cost-effective applications of UHPC in modern construction practices.