Preparation and characterization of PVDF film with self-cleaning property

被引:0
|
作者
Zheng Z.-R. [1 ]
Gu Z.-Y. [1 ]
Huo R.-T. [1 ]
Ye Y.-H. [1 ]
Zhang Z.-Q. [1 ]
机构
[1] School of Textiles, Tianjin Polytechnic University
关键词
Chemical bath deposition; Chemical vapor deposition; Lotus effect; Self-cleaning property; Superhydrophobic property;
D O I
10.3969/j.issn.1007-9629.2010.01.008
中图分类号
学科分类号
摘要
Based on the lotus effect principle, polyvinylidene fluoride(PVDF) solution was used to construct the microstructure under certain preparation conditions, and the nanostructure was established by plasma enhancing chemical bath deposition. The structural morphology and hydrophobicity were explored by scanning electronic microscopy, atomic force microscopy, and contact angle measuring meter. The experimental results show that PVDF can form smooth microreliefs with diameter about 8 μm on the coating surface, and the water contact angle of PVDF film is 88°. The network nanostructure is constructed by chemical bath deposition(CBD) method, the contact angle and the sliding angle on this surface are 157° and 4°, respectively. Meanwhile, the nanostructure similar to bird claw is constructed by chemical vapor deposition(CVD) method, the contact angle and the sliding angle on this surface are 155° and 4°, respectively. Self-cleaning test shows that the PVDF film prepared by both CBD and CVD method has excellent self-cleaning property.
引用
收藏
页码:36 / 41+124
相关论文
共 17 条
  • [11] Deng Y., Lian Z.-J., Application of a new anti-dirty and self-cleaning surface treatment coating, Textile Auxiliaries, 22, 9, pp. 25-27, (2005)
  • [12] Teshima K., Sugimura H., Inoue Y., Et al., Ultra-water-repellent poly(ethylene terephthalate) substrates, Langmuir, 19, 25, pp. 10624-10627, (2003)
  • [13] Gao L.C., McCarthy T.J., A perfectly hydrophobic surface, Journal of the American Chemical Society, 128, 28, pp. 9052-9053, (2006)
  • [14] Zhou N.-L., Introduction of the Organosilicon Polymer, (2000)
  • [15] Fisher T., XPS database: Element or energy
  • [16] Li X.M., Reinhoudt D., Crego-Calama M., What do we need for a superhydrophobic surface? A review on the recent progress in the preparation of superhydrophobic surfaces, Chemical Society Review, 36, 8, pp. 1350-1368, (2007)
  • [17] Butz V., Elzer A., Differentiation of nano-structured and conventionally water repellent textiles, Melliand Textilberichte International Textile Reports, 88, 9, pp. 672-674, (2007)