Effect of minerals on semi-coke combustion characteristics of maceral with different reducibility

被引:0
|
作者
Zhao Y. [1 ,2 ]
Hu H. [1 ]
Jin L. [1 ]
Wei X. [2 ]
机构
[1] Institute of Coal Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, Liaoning
[2] School of Chemical Engineering, China University of Mining and Technology, Xuzhou, 221116, Jiangsu
来源
Huagong Xuebao/CIESC Journal | 2019年 / 70卷 / 08期
关键词
Coal combustion; Maceral; Mineral matter; Pyrolysis; Reactivity; Reducibility;
D O I
10.11949/0438-1157.20190205
中图分类号
学科分类号
摘要
The effects of intrinsic minerals and three inorganic components (CaO, Fe2O3 and Al2O3) on the semi-coke combustion reactivity of maceral with different reducibility were investigated on a thermogravimetric analyzer. The results indicated that the combustion reactivity of maceral chars from the weakly reductive coal is better than that from the reductive coal. The inherent mineral matter of vitrinite reduces the ignition temperature of vitrinite chars, while the inherent mineral matter of inertinite shows obvious inhibition effect on their chars combustion reaction. Three added mineral matter inhibit the combustion reaction of maceral chars from the reductive coal, and the relative inhibiton sequence could be described as follows: Al2O3>CaO>Fe2O3, while CaO has a little catalytic effect on the combustion reaction of maceral chars from the weakly reductive coal, and the inhibition effect of Al2O3 and Fe2O3 on the combustion reaction of maceral chars from the weakly reductive coals is lower than that on the combustion reaction of maceral chars from the reductive coal. © All Right Reserved.
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页码:2946 / 2953
页数:7
相关论文
共 36 条
  • [1] Sun H.Q., Qu S.J., Wang L.B., Present situation of semi-coke production and utilization, Clean Coal Technology, 14, 6, pp. 62-65, (2008)
  • [2] Zhang J.P., Wang C.A., Jia X.W., Et al., Co-combustion characteristics and kinetic analysis of semi-coke and bituminous, CIESC Journal, 69, 8, pp. 3611-3618, (2018)
  • [3] Shen G.D., Wang Z.Q., Wu J.L., Et al., Combustion characteristics of low-rank coal chars in O<sub>2</sub>/CO<sub>2</sub>, O<sub>2</sub>/N<sub>2</sub> and O<sub>2</sub>/Ar by TGA, Journal of Fuel Chemistry and Technology, 44, 9, pp. 1066-1073, (2016)
  • [4] Sun Q.L., Li W., Li B.Q., Combustion reactivity of char from pyrolysis of Shenmu macerals, Journal of Chemical Industry and Engineering(China), 53, 1, pp. 92-95, (2002)
  • [5] Su S., Pohl J.H., Holcombe D., A proposed maceral index to predict combustion behavior of coal, Fuel, 80, 5, pp. 699-706, (2001)
  • [6] Cai H.Y., Kaniyoti R., Effect of changing inertinite concentration on pyrolysis yields and char reactivities of two South African coals, Energy & Fuels, 9, 6, pp. 956-961, (1995)
  • [7] Lu J.G., Study on combustion characteristics of four Chinese coal macerals by means of themogravimetriy, Journal of Fuel Chemistry and Technology, 24, 4, pp. 329-334, (1996)
  • [8] Borrego A.G., Alvarez D., Menendez R., Effects of inertinite content in coal on char structure and combustion, Energy & Fuels, 11, 3, pp. 702-708, (1997)
  • [9] Oka N., Murayama T., Matsuoka H., The influence of rank and maceral composition on ignition and char burnout of pulverized coal, Fuel Processing Technology, 15, 1, pp. 213-224, (1987)
  • [10] Liu Q.R., Hu H.Q., Zhou Q., Et al., Effect of inorganic mineral on reactivity and kinetics of coal pyrolysis, Fuel, 83, 6, pp. 713-718, (2004)