Self-Assembled 8-Ti-Containing Polyoxomolybdate for the Photocatalytic Hydrogen Evolution

被引：0

作者：

Wang, Wenyu ^{[1
]}

Liu, Sen ^{[1
]}

Ma, Pengtao ^{[1
]}

Wang, Jingping ^{[1
]}

Niu, Jingyang ^{[1
]}

机构：

[1] Henan Univ, Coll Chem & Mol Sci, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Henan, Peoples R China

来源：

INORGANIC CHEMISTRY | 2024年 / 63卷 / 43期

基金：

中国国家自然科学基金;

关键词：

NOBLE-METAL-FREE; POLYOXOMETALATE CATALYST; MOLECULAR-STRUCTURE; WATER; POLYOXOTUNGSTATES; STABILITY; MAGNETISM; CLUSTERS; CENTERS; VALENCE;

D O I：

10.1021/acs.inorgchem.4c03255

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An S-shaped 8-Ti-containing polyoxomolybdate (NH4)Cs2Na6H3[Ti-8(GeMo9O34)(2)(GeMo5O23)(2)]<middle dot>44H(2)O (1) has been prepared under the one-pot hydrothermal method and further characterized. According to single-crystal X-ray, compound 1 consists of two {GeMo9O34} and two {GeMo5O23} segments, which are linked with a {Ti8O34} cluster. Moreover, the {GeMo5O23} fragment is rare and the first discovery, which enriches the lacunary Keggin-type family and offers the possibility of obtaining new structures. Among all of the reported polyoxomolybdates, compound 1 has the highest nuclearity of Ti centers. From the photocatalytic hydrogen evolution studies, compound 1 can be used as the heterogeneous catalyst with an H-2 evolution rate of 2392.6 mu mol g(-1) h(-1) under minimally optimized conditions.

引用

页码：20625 / 20632

页数：8

共 50 条

[31] Self-assembled polymer phenylethnylcopper nanowires for photoelectrochemical and photocatalytic performance under visible light
Wei, Zhen
Hu, Jisong
Zhu, Kaijian
Wei, Weiqin
Ma, Xinguo
Zhu, Yongfa
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 226 : 616 - 623
[32] Synthesis of self-assembled CdS nanospheres and their photocatalytic activities by photodegradation of organic dye molecules
Yu, Zhou
Yin, Bosi
Qu, Fengyu
Wu, Xiang
[J]. CHEMICAL ENGINEERING JOURNAL, 2014, 258 : 203 - 209
[33] Controllable synthesis of self-assembled MoS2 hollow spheres for photocatalytic application
Liu, Xinchuan
Wang, Tinglan
Hu, Guangbo
Xu, Chao
Xiong, Yehan
Wang, Yongqian
[J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2018, 29 (01) : 753 - 761
[34] Synthesis, characterization and photocatalytic performance of self-assembled mesoporous TiO2 nanoparticles
Lin, Yuan-Chung
Liu, Shou-Heng
Syu, Han-Ren
Ho, Tsung-Han
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 95 : 300 - 304
[35] A regenerating self-assembled gold nanoparticle-containing electrochemical impedance sensor
Mahmoud, Amr M.
Tang, Thompson
Harrison, D. Jed
Lee, William E.
Jemere, Abebaw B.
[J]. BIOSENSORS & BIOELECTRONICS, 2014, 56 : 328 - 333
[36] Self-assembled tubular nanostructures of tris(8-quinolinolato)gallium(III)
Xie, Wanfeng
Wang, Fenggong
Fan, Jihui
Song, Hui
Wu, Zongyong
Yuan, Huimin
Jiang, Feng
Pang, Zhiyong
Han, Shenghao
[J]. RSC ADVANCES, 2015, 5 (94): : 77449 - 77453
[37] Self-assembled MoS2-GO Framework as an Efficient Cocatalyst of CuInZnS for Visible-Light Driven Hydrogen Evolution
Huang, Ting
Luo, Yuting
Chen, Wei
Yao, Jiacheng
Liu, Xiaoheng
[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (04): : 4671 - 4679
[38] Perylene-Containing Conjugated Microporous Polymers for Photocatalytic Hydrogen Evolution
Xu, Yunfeng
Mao, Na
Feng, Shi
Zhang, Chong
Wang, Feng
Chen, Yu
Zeng, Jinghui
Jiang, Jia-Xing
[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2017, 218 (14)
[39] Ionic assembled hybrid nanoparticle consisting of tin(IV) porphyrin cations and polyoxomolybdate anions, and photocatalytic hydrogen production by its visible light sensitization
Li, Changhong
Park, Ki-Min
Kim, Hee-Joon
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 60 : 8 - 11
[40] Photocatalytic hydrogen evolution by two comparable [ FeFe]- hydrogenase mimics assembled to the surface of ZnS
Song, Xiao-Wei
Wen, Hui-Min
Ma, Cheng-Bing
Hu, Ming-Qiang
Chen, Hui
Cui, Hong-Hua
Chen, Chang-Neng
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2014, 28 (04) : 267 - 273

← 1 2 3 4 5 →