Modulation strategies of metal-organic framework materials and its adsorption performance on typical heavy metal ions

被引：0
|
作者：
Chunshu X. [1 ,2 ]
Qingda Y. [2 ,3 ]
Yongxian L. [2 ]
Hualong Z. [2 ,4 ]
机构：
[1] Jinjiang Testing Institute of Quality and Metrology, Quanzhou, Fujian
[2] Advanced Polymer Materials Research Center of Sichuan University, Quanzhou, Fujian
[3] Xingye Leather Technology Co., Ltd, Quanzhou, Fujian
[4] National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu, Sichuan
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2023年 / 42卷 / 12期
关键词：
Adsorption; Heavy metal ions; Metal-organic framework materials; Nanostructure; Stability;
D O I：
10.16085/j.issn.1000-6613.2023-0130
中图分类号：
学科分类号：
摘要：
Metal-organic framework materials have the advantages of larger specific surface area, tunable pore and topological structures, and abundant active functional groups compared with traditional adsorbent materials, which can be used as high-performance adsorbents for the removal of heavy metal pollutants from water. In this paper, the structural characteristics of MOFs as adsorbents for water treatment were introduced. The regulatory strategies of MOFs based on metal node doping, side group functionalization and post-synthetic modification, such as porosity, surface activity, framework flexibility, water stability, scalability, biotoxicity and recyclability, were emphatically analyzed. Then, the research progress of MOFs in the removal of heavy metal ions was introduced, mainly on cationic heavy metal ions such as Pb(II) and Hg(II), and anionic oxyanions such as Cr(VI and As(III)/As(V) in water, and the mechanism of the action of MOFs in the removal of heavy metal ions in water was elaborated. Finally, the research directions of improving the water stability and adsorption performance of MOFs, balancing the relationship between the structural characteristics of MOFs, studying the migration and enrichment of MOFs in nature, and the controllable preparation of MOFs with low cost and high benefit were put forward for improving the reference of MOFs in the field of high-performance adsorption. © 2023 Chemical Industry Press. All rights reserved.
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页码：6518 / 6534
页数：16
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共 98 条
  • [11] TANG Chaochun, WANG Shunteng, HUANG Congxin, Et al., Research progress on adsorption of heavy metal ions in water by mesoporous metal organic framework materials, Chemical Industry and Engineering Progress, 41, 6, pp. 3263-3278, (2022)
  • [12] FU Qingshan, ZHANG Lei, ZHANG Wei, Et al., Research progress in metal-organic frame materials for adsorptive removal of contamination in wastewater, Materials Reports, 35, 11, pp. 11100-11110, (2021)
  • [13] YUSUFF Adeyinka, POPOOLA Lekan, BABATUNDE Esther, Adsorption of cadmium ion from aqueous solutions by copper-based metal organic framework: Equilibrium modeling and kinetic studies, Applied Water Science, 9, 4, (2019)
  • [14] ZHAO Liang, AZHAR Muhammad R, LI Xiaojie, Et al., Adsorption of cerium (Ⅲ) by HKUST-1 metal-organic framework from aqueous solution, Journal of Colloid and Interface Science, 542, pp. 421-428, (2019)
  • [15] ZHANG Zilong, CHEN Zhao, XIAO Yu, Et al., Study of the dynamic adsorption and the effect of the presence of different cations and anions on the adsorption of As(Ⅴ) on GUT-3, Applied Organometallic Chemistry, 35, 8, (2021)
  • [16] CAI Yawen, FENG Jinghua, TAN Xiaoli, Et al., Efficient capture of ReO<sup>-</sup><sub>4</sub> on magnetic amine-functionalized MIL-101(Cr): Revealing from selectivity to mechanism, Science of the Total Environment, 771, 1, (2021)
  • [17] HAN Bo, CHAKRABORTY Anutosh, Highly efficient adsorption desalination employing protonated-amino-functionalized MOFs, Desalination, 541, (2022)
  • [18] HAN Gang, QIAN Qihui, RODRIGUEZ Katherine Mizrahi, Et al., Hydrothermal synthesis of sub-20nm amine-functionalized MIL-101 (Cr) nanoparticles with high surface area and enhanced CO<sub>2</sub> uptake, Industrial & Engineering Chemistry Research, 59, 16, pp. 7888-7900, (2020)
  • [19] ELTAHER B J, SABOUNI R, GHOMMEM M, Et al., A comparative study of metal-organic frameworks for mercury detection in competitive aqueous environment, International Journal of Environmental Science and Technology, 19, pp. 12193-12210, (2022)
  • [20] LYU Shiwen, LIU Jingmin, LI Chunyang, Et al., A novel and universal metal-organic frameworks sensing platform for selective detection and efficient removal of heavy metal ions, Chemical Engineering Journal, 375, (2019)
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