Effects of Polycarboxylate Superplasticizer with β-Cyclodextrin on Properties of High Belite Calcium Sulphoaluminate Cement

被引:0
|
作者
Tang R. [1 ]
Wang Z. [1 ]
He H. [1 ]
Zhang L. [1 ]
Cai Y. [1 ]
Wang J. [1 ]
机构
[1] School of Materials Science and Engineering, Beijing University of Technology, Beijing
来源
Cailiao Daobao/Materials Review | 2018年 / 32卷 / 11期
关键词
High belite calcium sulphoaluminate cement; Polycarboxylate superplasticizer; Retardation; Setting time; Β-cyclodextrin;
D O I
10.11896/j.issn.1005-023X.2018.22.028
中图分类号
学科分类号
摘要
High belite calcium sulphoaluminate cement (HBCSA) is a newly developed cementing material with broad application prospects for its excellent mechanical properties, high volume stability, good durability and anti efflorescence property. Howe-ver, it is difficult for common retarders to delay its rapid hydration effectively due to the rapid setting and hardening of HBCSA, which has become the bottleneck restricting the wide application of this kind of new cement. In order to control the setting time of HBCSA and extend its application scope, the retarding material suited for HBCSA was explored and discussed in this paper, and the mechanism of hydration hardening of HBCSA was revealed, as well as the effective control measures were put forward. It was found that the combination of polycarboxylate superplasticizer (PCE) and β-cyclodextrin(β-CD) had good retarding effect to HBCSA paste or mortar. The fluidity, setting time and strength of HBCSA mortar with the admixture were tested. Scanning electron microscope (SEM), X-ray diffraction (XRD) analyzer, total organic carbon (TOC) analyzer and hydration heat evolution of cement were carried out. The results showed that the adding of PCE and β-CD could slow down the crystallization rate of ettringite, the setting time of HBCSA cement paste was significantly prolonged, and the cement setting time was increased with the increment of retarder content. Adding PCE and β-CD had a positive effect on improving the fluidity of HBCSA and the strength of rubber in the middle and late stages. © 2018, Materials Review Magazine. All right reserved.
引用
收藏
页码:4000 / 4005
页数:5
相关论文
共 21 条
  • [1] Gartner E., Industrially interesting approaches to "low-CO<sub>2</sub>" cements, Cement and Concrete Research, 34, 9, (2004)
  • [2] Damtoft J.S., Lukasik J., Herfort D., Et al., Sustainable development and climate change initiatives, Cement and Concrete Research, 38, 2, (2008)
  • [3] Winnefeld F., Lothenbach B., Hydration of calcium sulfoaluminate cements-experimental findings and thermodynamic modeling, Cement and Concrete Research, 40, 8, (2010)
  • [4] Lan M.Z., Xiang B.F., Zhou J., Et al., Hydration mechanism of rapid setting and hardening high belite calcium sulfoaluminate cement, Bulletin of the Chinese Ceram Society, 36, 8, (2017)
  • [5] Chen I.A., Hargis C.W., Juenger M.C.G., Understanding expansion in calcium sulfoaluminate-belite cements, Cement and Concrete Research, 42, 1, (2012)
  • [6] Chen I.A., Juenger M.C.G., Incorporation of coal combustion resi-duals into calcium sulfoaluminate-belite cement clinkers, Cement and Concrete Composites, 34, 8, (2012)
  • [7] Valenti G.L., Marroccoli M., Pace M.L., Et al., Discussion of the paper "Understanding expansion in calcium sulfoaluminate-belite cements" by I. A. Chen et Al., Cem. Concr Res, 42(2012)51-60, Cement and Concrete Research, 42, 11, (2012)
  • [8] Ferraris C.F., Obla K.H., Hill R., The influence of mineral admixtures on the rheology of cement paste and concrete, Cement and Concrete Research, 31, 2, (2001)
  • [9] Shi X., Yang Z., Liu Y., Et al., Strength and corrosion properties of Portland cement mortar and concrete with mineral admixtures, Construction and Building Materials, 25, 8, (2011)
  • [10] Lummer N.R., Plank J., Combination of lignosulfonate and AMPSR-co-NNDMA water retention agent-An example for dual synergistic interaction between admixtures in cement, Cement and Concrete Research, 42, 5, (2012)