Decoupling Analysis of Ignition Processes of Ammonia/N-Heptane Mixtures

被引:0
作者
Li, Zheng [1 ]
Zhang, Yilin [1 ]
Li, Jingrui [1 ,2 ,3 ]
Xu, Changchun [1 ,2 ,3 ]
Wen, Huabing [1 ]
Shen, Jianhua [3 ]
Jing, Haiguo [3 ]
Liu, Haifeng [4 ]
Wang, Xinyan [5 ]
Zhao, Hua [5 ]
机构
[1] Jiangsu Univ Sci & Technol, Sch Energy & Power, Zhenjiang 212003, Peoples R China
[2] Jiangsu Univ Sci & Technol, Sch Ship & Ocean Engn, Zhenjiang 212003, Peoples R China
[3] CSSC Marine Power Zhenjiang Co Ltd, Zhenjiang 212001, Peoples R China
[4] Tianjin Univ, State Key Lab Engine, Tianjin 300350, Peoples R China
[5] Brunel Univ London, Ctr Adv Powertrain & Fuels, London UB8 3PH, England
关键词
ignition delay time; chemical effect; thermal effect; ammonia/n-heptane mixtures; N-HEPTANE; ENGINE; FUEL; COMBUSTION; LAMINAR;
D O I
10.3390/en17194938
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
To further understand the influence of n-heptane on the ignition process of ammonia, an isotope labeling method was applied in the current investigation to decouple the influence of the chemical effect, the thermal effect, and the effect of O radical from the oxidation of n-heptane on the ignition delay times (IDTs) of ammonia. An analysis of the time evolution of fuel, analysis of the time evolution of temperature, rate of consumption and production (ROP) analysis, and sensitivity analysis were conducted to gain a further understanding of the mechanism of the influence of the chemical effect, the thermal effect, and the effect of O radical on the ignition of ammonia. The results showed that the negative temperature coefficient (NTC) behavior of n-heptane is mitigated by the blending of ammonia, and this mitigated effect of ammonia is mainly due to the chemical effect. The IDTs of ammonia under low and medium temperatures are significantly shortened by the chemical effect at a n-heptane mass fraction of 10%. The promoting effect of the chemical effect decreases when the n-heptane mass fraction increases. The time evolution of n-heptane for NC7H16/ND3-G can be classified into three stages at 800 K, and the rapid consumption stage is mitigated by an increase in temperature. The rapid consumption stage is suppressed by the chemical effect of ammonia, while O radical has a promoting effect on the rapid consumption stage. The chemical effect will enhance the sensitivities of reactions associated with ammonia. As the n-heptane mass fraction increases, the sensitivities of reactions associated with n-heptane are enhanced. Correspondingly, the effect of reactions associated with ammonia is weakened. When the n-heptane mass fraction is 30%, only reactions related to n-heptane have a great influence on the ignition of ammonia/n-heptane fuel blends under the thermal effect + the effect of O radical or only the thermal effect.
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页数:23
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