Sustainable recycling of benzoic acid production waste: Green and highly efficient methods to separate and recover high value-added conjugated aromatic compounds from industrial residues

被引：0

作者：

School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan 030006, China ^{[1
]}

不详 ^{[2
]}

不详 ^{[3
]}

机构：

[1] School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006

[2] Department of Chemical Engineering, Texas Tech University, Sixth and Canton, Lubbock

[3] Sphinx Scientific Laboratory Corporation, Sycamore, IL 60178

来源：

ACS Sustainable Chem. Eng. | 2013年 / 8卷 / 974-981期

关键词：

6H-Benzo[c]chromen-6-one; 9-Fluorenone; Benzoic acid industrial residue; Biphenyl carboxylic acids; Sustainable chemistry;

D O I：

10.1021/sc400059j

中图分类号：

学科分类号：

摘要：

Industrial residues formed in the industrial production of benzoic acid by cobalt-catalyzed oxidation of toluene are traditionally disposed as waste materials and often burnt or buried. It therefore may become a significant source of environmental pollution. In this report, we describe simple techniques to obtain high value conjugated aromatic compounds, including 9-fluorenone, 6H-benzo[c]chromen-6-one, biphenyl-3-carboxylic acid, and biphenyl-4-carboxylic acid, from benzoic acid industrial residue using inexpensive alkalis and acids. The separation methods involve simple and mild procedures with high economic effectiveness and low environmental contamination. © 2013 American Chemical Society.

引用

页码：974 / 981

页数：7

共 35 条

[1]

Sugranez R., Cruz-Yusta M., Marmol I., Martin F., Morales J., Sanchez L., Use of industrial waste for the manufacturing of sustainable building materials, ChemSusChem, 5, 4, pp. 694-699, (2012)

[2]

Lange J.-P., Sustainable chemical manufacturing: A matter of resources, wastes, hazards, and costs, ChemSusChem, 2, 6, pp. 587-592, (2009)

[3]

Warth A.D., Effect of benzoic acid on glycolytic metabolite levels and intracellular pH in Saccharomyces cerevisiae, Appl. Environ. Microbiol., 57, 12, pp. 3415-3417, (1991)

[4]

Jayaram S., Dharmesh S.M., Assessment of antioxidant potentials of free and bound phenolics of Hemidesmus indicus (L) R.Br against oxidative damage, Pharmacognosy Res., 3, 4, pp. 225-231, (2011)

[5]

Lv H.-S., Zhao B.-X., Li J.-K., Xia Y., Lian S., Liu W.-Y., Gong Z.-L., The synthesis, characterization and optical properties of novel, substituted, pyrazoly 1,3,4-oxadiazole derivatives, Dyes Pigm., 86, 1, pp. 25-31, (2010)

[6]

Chaves C.A., MacHado A.L., Carlos I.Z., Giampaolo E.T., Pavarina A.C., Vergani C.E., Cytotoxicity of monomers, plasticizer and degradation by-products released from dental hard chairside reline resins, Dent. Mater., 26, 10, pp. 1017-1023, (2010)

[7]

Tada A., Geng Y.-F., Nakamura M., Wei Q.-S., Hashimoto K., Tajima K., Interfacial modification of organic photovoltaic devices by molecular self-organization, Phys. Chem. Chem. Phys., 14, 11, pp. 3713-3724, (2012)

[8]

Arceo E., Ellman J.A., Bergman R.G., A direct, biomass-based synthesis of benzoic acid: Formic acid-mediated deoxygenation of the glucose-derived materials quinic acid and shikimic acid, ChemSusChem, 3, 7, pp. 811-813, (2010)

[9]

Yoshino Y., Hayashi Y., Iwahama T., Sakaguchi S., Ishii Y., Catalytic oxidation of alkylbenzenes with molecular oxygen under normal pressure and temperature by N-hydroxyphthalimide combined with Co(OAc) <sub>2</sub>, J. Org. Chem., 62, 20, pp. 6810-6813, (1997)

[10]

Zhu J., Tsang S.C., Micellar catalysis for partial oxidation of toluene to benzoic acid in supercritical CO<sub>2</sub>: Effects of fluorinated surfactants, Catal. Today, 81, 4, pp. 673-679, (2003)

← 1 2 3 4 →